A Surface Chemical Reaction in Organic-Inorganic Materials Using a New Chemical Evaporation System

被引：10

作者：

Kim, Seong Jun ^{[1
,2
]}

Myung, Sung ^{[1
]}

Song, Wooseok ^{[1
]}

Min, Bok Ki ^{[1
]}

Hong, Seong-Jin ^{[1
]}

Chung, Myungwoo ^{[4
]}

Kim, Hyunjung ^{[4
]}

Kong, Ki-Jeong ^{[1
]}

Lim, Jongsun ^{[1
]}

Chung, Taek Mo ^{[1
]}

An, Ki-Seok ^{[1
,3
]}

机构：

[1] Korea Res Inst Chem Technol, Thin Film Mat Res Ctr, Taejon 305343, South Korea

[2] Univ Sci & Technol, Nanomat Sci & Engn, Taejon 305350, South Korea

[3] Univ Sci & Technol, Chem Convergence Mat, Taejon 305350, South Korea

[4] Sogang Univ, Dept Phys, Seoul 121742, South Korea

来源：

CHEMISTRY OF MATERIALS | 2015年 / 27卷 / 13期

关键词：

ATOMIC LAYER DEPOSITION; PORPHYRIN; METALATION; TETRAPHENYLPORPHYRIN; COORDINATION; COMPLEX; FILMS;

D O I：

10.1021/acs.chemmater.5b00377

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report the surface reaction that occurs in organic inorganic thin films using a hybrid deposition system that combines thermal evaporation (TE) and metalation processes. Growth of a smooth, uniform organic-inorganic hybrid thin film was demonstrated, and the occurrence of a self-limited surface reaction between the organic semiconductor and the inorganic metal atom during the metalation process was confirmed with X-ray photoelectron spectroscopy and Raman analysis. In this study, we utilized a hybrid deposition system that combined TE and vapor-phase metalation to create an organic-inorganic hybrid thin film. Experimental data and theoretical simulation of a model system are also provided to explain the barrierless reaction that occurs during synthesis of a zinc tetraphenylporphyrin thin film. This process can be utilized to increase the flexibility for the advanced synthesis of organic-inorganic hybrid thin films.

引用

页码：4546 / 4551

页数：6

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