Recent advances in dialkyl carbonates synthesis and applications

被引:310
作者
Huang, Shouying [1 ]
Yan, Bing [1 ]
Wang, Shengping [1 ]
Ma, Xinbin [1 ]
机构
[1] Tianjin Univ, Sch Chem Engn & Technol, Collaborat Innovat Ctr Chem Sci & Engn, Key Lab Green Chem Technol,Minist Educ, Tianjin 300072, Peoples R China
基金
美国国家科学基金会;
关键词
PHASE OXIDATIVE CARBONYLATION; EFFICIENT HETEROGENEOUS CATALYST; ONE-POT SYNTHESIS; AMINO-FUNCTIONALIZED MCM-41; IONIC LIQUID BMIMBF4; HIGH-YIELD SYNTHESIS; CU-Y ZEOLITE; DIMETHYL CARBONATE; DIETHYL CARBONATE; ETHYLENE CARBONATE;
D O I
10.1039/c4cs00374h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Dialkyl carbonates are important organic compounds and chemical intermediates with the label of "green chemicals'' due to their moderate toxicity, biodegradability for human health and environment. Indeed, owing to their unique physicochemical properties and versatility as reagents, a variety of phosgene-free processes derived from CO or CO2 have been explored for the synthesis of dialkyl carbonates. In this critical review, we highlight the recent achievements (since 1997) in the synthesis of dialkyl carbonates based on CO and CO2 utilization, particularly focusing on the catalyst design and fabrication, structure-function relationship, catalytic mechanisms and process intensification. We also provide an overview regarding the applications of dialkyl carbonates as fuel additives, solvents and reaction intermediates (i.e. alkylating and carbonylating agents). Additionally, this review puts forward the substantial challenges and opportunities for future research associated with dialkyl carbonates.
引用
收藏
页码:3079 / 3116
页数:38
相关论文
共 426 条
[1]   Preparation and characterization of MgO-CeO2 mixed oxide catalysts by modified coprecipitation using ionic liquids for dimethyl carbonate synthesis [J].
Abimanyu, Haznan ;
Ahn, Byoung Sung ;
Kim, Chang Soo ;
Yoo, Kye Sang .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2007, 46 (24) :7936-7941
[2]   Synthesis of dimethyl carbonate by transesterification with various MgO-CeO2 mixed oxide catalysts [J].
Abimanyu, Haznan ;
Kim, Chang Soo ;
Ahn, Byoung Sung ;
Yoo, Kye Sang .
CATALYSIS LETTERS, 2007, 118 (1-2) :30-35
[3]   Synthesis of diethyl carbonate from ethyl carbamate and ethanol over ZnO-PbO catalyst [J].
An, Hualiang ;
Zhao, Xinqiang ;
Guo, Lian ;
Jia, Chunyao ;
Yuan, Baoguo ;
Wang, Yanji .
APPLIED CATALYSIS A-GENERAL, 2012, 433 :229-235
[4]   Origins, current status, and future challenges of green chemistry [J].
Anastas, PT ;
Kirchhoff, MM .
ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (09) :686-694
[5]   The decomposition of dimethyl carbonate over copper zeolite catalysts [J].
Anderson, SA ;
Manthata, S ;
Root, TW .
APPLIED CATALYSIS A-GENERAL, 2005, 280 (02) :117-124
[6]   Investigation of the effect of carbon monoxide on the oxidative carbonylation of methanol to dimethyl carbonate over Cu+X and Cu+ZSM-5 zeolites [J].
Anderson, SA ;
Root, TW .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 220 (02) :247-255
[7]   Kinetic studies of carbonylation of methanol to dimethyl carbonate over Cu+X zeolite catalyst [J].
Anderson, SA ;
Root, TW .
JOURNAL OF CATALYSIS, 2003, 217 (02) :396-405
[8]  
[Anonymous], 2012, Green Solvents I
[9]   Comparative study between gas phase and liquid phase for the production of DMC from methanol and CO2 [J].
Aouissi, Ahmed ;
Al-Deyab, Salem S. .
JOURNAL OF NATURAL GAS CHEMISTRY, 2012, 21 (02) :189-193
[10]   Reactivity of Heteropolytungstate and Heteropolymolybdate Metal Transition Salts in the Synthesis of Dimethyl Carbonate from Methanol and CO2 [J].
Aouissi, Ahmed ;
Al-Deyab, Salem S. ;
Al-Owais, Ahmad ;
Al-Amro, Amro .
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2010, 11 (07) :2770-2779