Safety improvement of lithium ion batteries by organo-fluorine compounds

被引：34
作者：
Matsuda, Yuki [1 ]
Nakajima, Tsuyoshi [1 ]
Ohzawa, Yoshimi [1 ]
Koh, Meiten [2 ]
Yamauchi, Akiyoshi [2 ]
Kagawa, Michiru [2 ]
Aoyama, Hirokazu [2 ]
机构：
[1] Aichi Inst Technol, Dept Appl Chem, Toyota 4700392, Japan
[2] Daikin Ind Ltd, Osaka 5668585, Japan
来源：
JOURNAL OF FLUORINE CHEMISTRY | 2011年 / 132卷 / 12期
关键词：
Organo-fluorine compound; Thermal stability; Oxidation stability; Graphite electrode; Lithium ion battery; SOLVENT-CONTAINING ELECTROLYTES; FLAME-RETARDANT ADDITIVES; PHENYL DIPHENYL PHOSPHATE; THERMAL-STABILITY; ELECTROCHEMICAL PERFORMANCE; TRIMETHYL PHOSPHATE; NONFLAMMABLE ELECTROLYTES; ETHYLENE CARBONATE; ALKYL PHOSPHATES; TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE;
D O I：
10.1016/j.jfluchem.2011.07.019
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Thermal stability, electrochemical oxidation stability and charge/discharge characteristics of natural graphite powder were investigated by mixing of five fluoro-carbonates with 1 mol/L LiClO4-EC/DEC/PC (1:1:1 vol.). DSC study revealed that thermal stability of the electrolyte solution was improved by mixing of fluoro-carbonates by 10.0-33.3 vol.%. Electrochemical oxidation stability was also improved. Oxidation currents for Pt electrode significantly decreased by mixing of fluoro-carbonates. In the fluoro-carbonate-mixed electrolyte solutions, electrochemical reduction of PC decreased with increasing concentration of fluoro-carbonate and current density. As a result, first coulombic efficiency for natural graphite electrode increased, that is, irreversible capacity decreased in the fluoro-carbonate-mixed solutions. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：1174 / 1181
页数：8
相关论文
共 53 条
[1]   Thermal Stability and Electrochemical Properties of Fluorine Compounds as Nonflammable Solvents for Lithium-Ion Batteries [J].
Achiha, Takashi ;
Nakajima, Tsuyoshi ;
Ohzawa, Yoshimi ;
Koh, Meiten ;
Yamauchi, Akiyoshi ;
Kagawa, Michiru ;
Aoyama, Hirokazu .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2010, 157 (06) :A707-A712
[2]   Electrochemical Behavior of Nonflammable Organo-Fluorine Compounds for Lithium Ion Batteries [J].
Achiha, Takashi ;
Nakajima, Tsuyoshi ;
Ohzawa, Yoshimi ;
Koh, Meiten ;
Yamauchi, Akiyoshi ;
Kagawa, Michiru ;
Aoyama, Hirokazu .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (06) :A483-A488
[3]   A comparative study of synthetic graphite and Li electrodes in electrolyte solutions based on ethylene carbonate dimethyl carbonate mixtures [J].
Aurbach, D ;
Markovsky, B ;
Shechter, A ;
EinEli, Y ;
Cohen, H .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (12) :3809-3820
[4]   A novel flame retardant and film-forming electrolyte additive for lithium ion batteries [J].
Chen, Shiyu ;
Wang, Zhaoxiang ;
Zhao, Hailei ;
Qiao, Hongwei ;
Luan, Helin ;
Chen, Liquan .
JOURNAL OF POWER SOURCES, 2009, 187 (01) :229-232
[5]   Lithium Difluoro(oxalato)borate as Additive to Improve the Thermal Stability of Lithiated Graphite [J].
Chen, Zonghai ;
Qin, Yan ;
Liu, Jun ;
Amine, K. .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2009, 12 (04) :A69-A72
[6]   Allyl-substituted triazines as additives for enhancing the thermal stability of Li-ion batteries [J].
Cho, Young-Hyun ;
Kim, Ketack ;
Ahn, Seyoung ;
Liu, Hua Kun .
JOURNAL OF POWER SOURCES, 2011, 196 (03) :1483-1487
[7]   Quantitative studies on the thermal stability of the interface between graphite electrode and electrolyte [J].
Doi, Takayuki ;
Zhao, Liwei ;
Zhou, Mingjiong ;
Okada, Shigeto ;
Yamaki, Jun-ichi .
JOURNAL OF POWER SOURCES, 2008, 185 (02) :1380-1385
[8]   Effects of additives on thermal stability of Li ion cells [J].
Doughty, DH ;
Roth, EP ;
Crafts, CC ;
Nagasubramanian, G ;
Henriksen, G ;
Amine, K .
JOURNAL OF POWER SOURCES, 2005, 146 (1-2) :116-120
[9]   On the Thermal Behavior of Lithium Intercalated Graphites [J].
Haik, Ortal ;
Ganin, Svetlana ;
Gershinsky, Gregory ;
Zinigrad, Ella ;
Markovsky, Boris ;
Aurbach, Doron ;
Halalay, I. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2011, 158 (08) :A913-A923
[10]   The cooperative effect of tri(β-chloromethyl) phosphate and cyclohexyl benzene on lithium ion batteries [J].
He, Yan-Bing ;
Liu, Qiang ;
Tang, Zhi-Yuan ;
Chen, Yu-Hong ;
Song, Quan-Sheng .
ELECTROCHIMICA ACTA, 2007, 52 (11) :3534-3540
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