MXene;
MnCo2O4;
High specific capacitance;
Supercapacitor;
TITANIUM CARBIDE;
ELECTRODE;
FILMS;
PHASE;
D O I:
10.1016/j.est.2021.103906
中图分类号:
TE [石油、天然气工业];
TK [能源与动力工程];
学科分类号:
0807 ;
0820 ;
摘要:
MXene is an ideal candidate material for supercapacitor electrode due to their unique accordion-like structure, large specific surface area, remarkable conductivity and excellent chemical stability. Due to the large surface energy between layers, it is easy to stack between layers of MXene, and the energy storage field between the layers cannot be fully utilized. Therefore, increasing the interlayer spacing of MXene is a research focus to enhance electrochemical performance. The spinel ternary metal oxide MnCo2O4 have been extensively investigated as electrode materials due to low-cost and highly theoretical capacitances. Moreover, manganese ions can improve the rate performance of the material, and cobalt ions have a higher oxidation potential. Herein, the interlayer spacing of MXene is increased by introducing nano-scale MnCo2O4 particles. The as-prepared optimal electrode material exhibits a specific capacity of 806.7 F g(-1) at a current density of 1 A g(-1), and excellent cycle stability. The asymmetric supercapacitor device is assembled by the obtained electrode as the positive electrode and activated carbon as the negative electrode, which the device can provide energy density of 26.8 Wh kg(-1)& nbsp;at power density of 2.88 kW kg(-1)& nbsp;with excellent cycle stability (93.8% capacity retention after 5000 cycles at a current density of 5 A g(-1)). The research proposes a simple hydrothermal method was used to prepare a high-performance MXene-based supercapacitor.
机构:
East China Jiaotong Univ, Sch Civil Engn & Architecture, Nanchang 330013, Jiangxi, Peoples R ChinaEast China Jiaotong Univ, Sch Civil Engn & Architecture, Nanchang 330013, Jiangxi, Peoples R China
Zhou, Shuangxi
Luo, Xiangwei
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机构:
Guilin Univ Elect Technol, Guangxi Key Lab Informat Mat, Guilin 541004, Peoples R ChinaEast China Jiaotong Univ, Sch Civil Engn & Architecture, Nanchang 330013, Jiangxi, Peoples R China
Luo, Xiangwei
Chen, Lin
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h-index: 0
机构:
Pingxiang Univ, Dept Mat & Chem Engn, Pingxiang 337055, Peoples R ChinaEast China Jiaotong Univ, Sch Civil Engn & Architecture, Nanchang 330013, Jiangxi, Peoples R China
Chen, Lin
Xu, Changjie
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h-index: 0
机构:
East China Jiaotong Univ, Sch Civil Engn & Architecture, Nanchang 330013, Jiangxi, Peoples R ChinaEast China Jiaotong Univ, Sch Civil Engn & Architecture, Nanchang 330013, Jiangxi, Peoples R China
Xu, Changjie
Yan, Dongliang
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机构:
Guilin Univ Elect Technol, Guangxi Key Lab Informat Mat, Guilin 541004, Peoples R ChinaEast China Jiaotong Univ, Sch Civil Engn & Architecture, Nanchang 330013, Jiangxi, Peoples R China
机构:
Nanomaterials Laboratory, Department of Physics, Alagappa University, Karaikudi, 630003, Tamil NaduNanomaterials Laboratory, Department of Physics, Alagappa University, Karaikudi, 630003, Tamil Nadu
Saravanakumar B.
Ravi G.
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机构:
Nanomaterials Laboratory, Department of Physics, Alagappa University, Karaikudi, 630003, Tamil NaduNanomaterials Laboratory, Department of Physics, Alagappa University, Karaikudi, 630003, Tamil Nadu
Ravi G.
Ganesh V.
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机构:
Electrodics and Electrocatalysis (EEC) Division, CSIR–Central Electrochemical Research Institute (CSIR–CECRI), Karaikudi, 630003, Tamil NaduNanomaterials Laboratory, Department of Physics, Alagappa University, Karaikudi, 630003, Tamil Nadu
Ganesh V.
Guduru R.K.
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机构:
Department of Mechanical Engineering, Lamar University, Beaumont, 77710, TXNanomaterials Laboratory, Department of Physics, Alagappa University, Karaikudi, 630003, Tamil Nadu
Guduru R.K.
Yuvakkumar R.
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h-index: 0
机构:
Nanomaterials Laboratory, Department of Physics, Alagappa University, Karaikudi, 630003, Tamil NaduNanomaterials Laboratory, Department of Physics, Alagappa University, Karaikudi, 630003, Tamil Nadu
机构:
S Cent Univ Nationalities, Key Lab Catalysis & Mat Sci, State Ethn Affairs Commiss, Wuhan 430074, Hubei Province, Peoples R China
S Cent Univ Nationalities, Minist Educ, Wuhan 430074, Hubei Province, Peoples R ChinaS Cent Univ Nationalities, Key Lab Catalysis & Mat Sci, State Ethn Affairs Commiss, Wuhan 430074, Hubei Province, Peoples R China
Liu, Haowen
Wang, Jin
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机构:
S Cent Univ Nationalities, Minist Educ, Wuhan 430074, Hubei Province, Peoples R ChinaS Cent Univ Nationalities, Key Lab Catalysis & Mat Sci, State Ethn Affairs Commiss, Wuhan 430074, Hubei Province, Peoples R China