An overview of palladium-catalyzed trifluoromethylation reactions

被引：7

作者：

Arun, Roy ^{[1
]}

Stiniya, Sebastian ^{[2
]}

Saranya, Padinjare Veettil ^{[2
]}

Anilkumar, Gopinathan ^{[2
]}

机构：

[1] Christ Coll Autonomous, Dept Chem, Trichur 680125, Kerala, India

[2] Mahatma Gandhi Univ, Sch Chem Sci, Priyadarsini Hills PO, Kottayam 686560, Kerala, India

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2022年 / 979卷

关键词：

Arenes; Aryl halides; Fluorination; Palladium; Trifluoromethylation; PD(II)-CATALYZED ORTHO-TRIFLUOROMETHYLATION; CARBONYLATIVE CYCLIZATION REACTION; TRIFLUOROACETIMIDOYL CHLORIDES; 2,3,3-TRIFLUOROALLYLIC CARBONATES; INTRAMOLECULAR CONSTRUCTION; ARYL IODIDES; PD; ARENES; DERIVATIVES; FLUORINE;

D O I：

10.1016/j.jorganchem.2022.122492

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

C-CF(3 )bond and its methods of formation could gather great attention in the area of organofluorine chemistry because of its applications in various fields like pharmaceuticals, material science and agrochemicals. Several palladium-catalyzed trifluoromethylation reactions could be developed in the last decade. Broad functional group tolerance and good selectivity make palladium catalysts extremely useful in industrial manufacturing processes. This review provides an overview of various Pd-catalyzed trifluormethylation reactions covering literatures up to 2021. (c) 2022 Elsevier B.V. All rights reserved.

引用

页数：61

共 101 条

[81] Nickel-Catalyzed C-H Trifluoromethylation of Electron-Rich Heteroarenes [J].

Wu, Yun ;

Zhang, Hao-Ran ;

Jin, Ruo-Xing ;

Lan, Quan ;

Wang, Xi-Sheng .

ADVANCED SYNTHESIS & CATALYSIS, 2016, 358 (22) :3528-3533

[82] Ligand Free Palladium-Catalyzed Synthesis of α-Trifluoromethylacrylic Acids and Related Acrylates by Three-Component Reaction [J].

Xiao, Pan ;

Pannecoucke, Xavier ;

Bouillon, Jean-Philippe ;

Couve-Bonnaire, Samuel .

ADVANCED SYNTHESIS & CATALYSIS, 2020, 362 (04) :949-954

[83] Palladium(II)-Catalyzed Directed Trifluoromethylthiolation of Unactivated C(sp3)-H Bonds [J].

Xiong, Heng-Ying ;

Besset, Tatiana ;

Cahard, Dominique ;

Pannecoucke, Xavier .

JOURNAL OF ORGANIC CHEMISTRY, 2015, 80 (08) :4204-4212

[84] Palladium-Catalyzed Trifluoromethylthiolation of Aryl C-H Bonds [J].

Xu, Chunfa ;

Shen, Qilong .

ORGANIC LETTERS, 2014, 16 (07) :2046-2049

[85] THE TRIFLUOROMETHYL GROUP IN MEDICINAL CHEMISTRY [J].

YALE, HL .

JOURNAL OF MEDICINAL & PHARMACEUTICAL CHEMISTRY, 1959, 1 (02) :121-133

[86] Palladium-Catalyzed Cascade Carbonylative Cyclization Reaction of Trifluoroacetimidoyl Chlorides and 2-Iodoanilines: Toward 2-(Trifluoromethyl)quinazolin-4(3H)-ones Synthesis [J].

Yang, Hefei ;

Wang, Le-Cheng ;

Wang, Wei-Feng ;

Chen, Zhengkai ;

Wu, Xiao-Feng .

CHEMISTRYSELECT, 2020, 5 (35) :11072-11076

[87] Trifluoromethylthiolation of Aryl Iodides and Bromides Enabled by a Bench-Stable and Easy-To-Recover Dinuclear Palladium(I) Catalyst [J].

Yin, Guoyin ;

Kalvet, Indrek ;

Schoenebeck, Franziska .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (23) :6809-6813

[88] Highly ortho-Selective Trifluoromethylthiolation Reactions using a Ligand Exchange Strategy [J].

Yin, Weiyu ;

Wang, Zhaofeng ;

Huang, Yong .

ADVANCED SYNTHESIS & CATALYSIS, 2014, 356 (14-15) :2998-3006

[89] Recent advances in Palladium(II)-catalyzed activation of aromatic ring C-H bonds [J].

Yun, Yin-ling ;

Yang, Jie ;

Miao, Yu-hang ;

Sun, Jie ;

Wang, Xiao-jing .

JOURNAL OF SAUDI CHEMICAL SOCIETY, 2020, 24 (02) :151-185

[90] Direct Cupration of Fluoroform [J].

Zanardi, Alessandro ;

Novikov, Maxim A. ;

Martin, Eddy ;

Benet-Buchholz, Jordi ;

Grushin, Vladimir V. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (51) :20901-20913

← 2 3 4 5 6 7 8 9 10 11 →