An overview of palladium-catalyzed trifluoromethylation reactions

被引：7

作者：

Arun, Roy ^{[1
]}

Stiniya, Sebastian ^{[2
]}

Saranya, Padinjare Veettil ^{[2
]}

Anilkumar, Gopinathan ^{[2
]}

机构：

[1] Christ Coll Autonomous, Dept Chem, Trichur 680125, Kerala, India

[2] Mahatma Gandhi Univ, Sch Chem Sci, Priyadarsini Hills PO, Kottayam 686560, Kerala, India

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2022年 / 979卷

关键词：

Arenes; Aryl halides; Fluorination; Palladium; Trifluoromethylation; PD(II)-CATALYZED ORTHO-TRIFLUOROMETHYLATION; CARBONYLATIVE CYCLIZATION REACTION; TRIFLUOROACETIMIDOYL CHLORIDES; 2,3,3-TRIFLUOROALLYLIC CARBONATES; INTRAMOLECULAR CONSTRUCTION; ARYL IODIDES; PD; ARENES; DERIVATIVES; FLUORINE;

D O I：

10.1016/j.jorganchem.2022.122492

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

C-CF(3 )bond and its methods of formation could gather great attention in the area of organofluorine chemistry because of its applications in various fields like pharmaceuticals, material science and agrochemicals. Several palladium-catalyzed trifluoromethylation reactions could be developed in the last decade. Broad functional group tolerance and good selectivity make palladium catalysts extremely useful in industrial manufacturing processes. This review provides an overview of various Pd-catalyzed trifluormethylation reactions covering literatures up to 2021. (c) 2022 Elsevier B.V. All rights reserved.

引用

页数：61

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