Decoration of Co/Co3O4 nanoparticles with Ru nanoclusters: a new strategy for design of highly active hydrogenation

被引：52
作者：
Zhu, Lihua [1 ]
Yang, Zhiqing [2 ]
Zheng, Jinbao [1 ]
Hu, Weiwei [2 ]
Zhang, Nuowei [1 ]
Li, Yunhua [1 ]
Zhong, Chuan-Jian [3 ]
Ye, Hengqiang [2 ]
Chen, Bing H. [1 ]
机构：
[1] Xiamen Univ, Dept Chem & Biochem Engn, Natl Engn Lab Green Prod Alcohols Ethers Esters, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China
[2] Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China
[3] SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA
来源：
JOURNAL OF MATERIALS CHEMISTRY A | 2015年 / 3卷 / 22期
基金：
中国国家自然科学基金;
关键词：
BENZENE HYDROGENATION; HETEROGENEOUS CATALYST; HIGH-PERFORMANCE; HYDROLYSIS; AROMATICS; OXIDATION; SUPPORT; ARENES; TIO2;
D O I：
10.1039/c5ta02452h
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Ru/Co/Co3O4/C (Ru nanoclusters-on-Co/Co3O4 nanoparticles) has an unexpected enhancement of activity for benzene hydrogenation which is about 2500 times higher than Ru-Co nanoalloy/C. Detailed nanostructure characterization of Ru/Co/Co3O4/C has revealed that the high activity originates from a synergetic multifunction of the catalytic Ru, Co and Co3O4 sites on the nanocluster/nanoparticle surfaces.
引用
收藏
页码：11716 / 11719
页数：4
相关论文
共 50 条
  • [21] Oxygen vacancies in Co3O4 promote CO2 photoreduction
    Zhang, Qi
    Yang, Pengju
    Zhang, Hongxia
    Zhao, Jianghong
    Shi, Hu
    Huang, Yamin
    Yang, Hengquan
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2022, 300
  • [22] Different Co-based MOFs templated synthesis of Co3O4 nanoparticles to degrade RhB by activation of oxone
    Pu, Jia-yi
    Wan, Jin-quan
    Wang, Yan
    Ma, Yong-wen
    RSC ADVANCES, 2016, 6 (94): : 91791 - 91797
  • [23] Morphology effect of In2O3/Co3O4 on Co-In2O3 interface formation to drive the hydrogenation of CO2 to methanol
    Lin, Daifeng
    Zheng, Weijie
    Lin, Sizhen
    Zhang, Lei
    Li, Wei
    Zhuo, Qian
    Yang, Wenqing
    Luo, Yongjin
    Qian, Qingrong
    Chen, Qinghua
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2024, 90 : 42 - 51
  • [24] Low temperature synthesis of Co3O4 and (Co1-x,Mnx)3O4 spinels nanoparticles
    Giovannelli, F.
    Marsteau, V.
    Zaghrioui, M.
    Autret, C.
    Delorme, F.
    ADVANCED POWDER TECHNOLOGY, 2017, 28 (05) : 1325 - 1331
  • [25] Hydrothermal Synthesis of Co(II) Complex, a Precursor for the Synthesis of Octahedral Co3O4 Nanoparticles :An Active Catalyst for the Removal of Cr(VI)
    Razmara, Zohreh
    Sanchooli, Esmael
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2019, 29 (06) : 2090 - 2102
  • [26] Roles of Al2O3 promoter for an enhanced structural stability of ordered-mesoporous Co3O4 catalyst during CO hydrogenation to hydrocarbons
    Koo, Hyun Mo
    Ahn, Chang-Il
    Lee, Dong Hyun
    Roh, Hyun-Seog
    Shin, Chae-Ho
    Kye, Hyoungsan
    Bae, Jong Wook
    FUEL, 2018, 225 : 460 - 471
  • [27] Photothermal catalyzed hydrogenation of carbon dioxide over porous nanosheet Co3O4
    Gu, Yujie
    Ding, Jie
    Tong, Xiao
    Yao, Hai
    Yang, Runyu
    Zhong, Qin
    JOURNAL OF CO2 UTILIZATION, 2022, 61
  • [28] Formation of Hollow Co3O4 Nanoparticles on Nitrogen-doped Porous Carbons for Highly Capacitive Performance
    Kim, Gi Mihn
    Park, Jae Hyun
    Lee, Jae W.
    CHEMISTRYSELECT, 2016, 1 (03): : 560 - 566
  • [29] CuO-NiO/Co3O4 hybrid nanoplates as highly active catalyst for ammonia borane hydrolysis
    Liao, Jinyun
    Feng, Yufa
    Lin, Weimin
    Su, Xinlong
    Ji, Shan
    Li, Liling
    Zhang, Wanling
    Pollet, Bruno G.
    Li, Hao
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2020, 45 (15) : 8168 - 8176
  • [30] Oxygen-deficient Co3O4 submicron porous sphere films as highly active supsercapacitor electrodes
    Yu, Zexin
    Ma, Yangzhou
    Liu, Meimei
    Huang, Xuanning
    Song, Chen
    Song, Guangsheng
    Liao, Hanlin
    Chen, Yao
    Sun, Lining
    SURFACE & COATINGS TECHNOLOGY, 2021, 405 (405)
12345