Nonvolatile memory with molecule-engineered tunneling barriers

被引:11
作者
Hou, Tuo-Hung [1 ]
Raza, Hassan [1 ]
Afshari, Kamran [1 ]
Ruebusch, Daniel J. [1 ]
Kan, Edwin C. [1 ]
机构
[1] Cornell Univ, Sch Elect & Comp Engn, Ithaca, NY 14853 USA
基金
美国国家科学基金会;
关键词
D O I
10.1063/1.2911741
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report a novel field-sensitive tunneling barrier by embedding C-60 in SiO2 for nonvolatile memory applications. C-60 is a better choice than ultrasmall nanocrystals due to its monodispersion. Moreover, C-60 provides accessible energy levels to prompt resonant tunneling through SiO2 at high fields. However, this process is quenched at low fields due to highest occupied molecular orbital (HOMO)-lowest unoccupied molecular orbital (LUMO) gap and large charging energy of C-60. Furthermore, we demonstrate an improvement of more than an order of magnitude in retention to program/erase time ratio for a metal nanocrystal memory. This shows promise of engineering tunnel dielectrics by integrating molecules in the future hybrid molecular-silicon electronics. (C) 2008 American Institute of Physics.
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页数:3
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