Complexes of cadmium(II), mercury(II) and lead(II) with quercetin-5′-sulfonic acid (QSA)

被引:0
作者
Kopacz, M [1 ]
Kuzniar, A [1 ]
机构
[1] Univ Technol, Fac Chem, Dept Inorgan & Analyt Chem, PL-35959 Rzeszow, Poland
关键词
complexes; quereetin-5 '-sulfonic acid (QSA); synthesis; thermal analysis; spectroscopic properties; antidotes against metals;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
QSA (C15H10O10S.5H(2)O), a ligand, which is non-toxic and well soluble in water, forms complex compounds with cations of toxic metals (Cd, Hg, Pb). New complex compounds with QSA:Cd(C15H9O10S)(2).10H(2)O, Hg(C15H9O10S)(2).8H(2)O, Pb(C15H9O10S)(2).8H(2)O and Pb(C15H8O10S).4H(2)O have been synthesized. Some of their physicochemical properties such as UV-VIS and infrared spectra, mass spectra, thermogravimetric analysis, and solubility were studied. It was found that the obtained compounds are sparingly soluble in water, which points out that QSA could be an antidote against cadmium, lead and mercury. The structures of the obtained compounds have been proposed.
引用
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页码:1777 / 1786
页数:10
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