(Ba(0.7)Sr(0.3))TiO(3) thin films with a typical thickness of 30 mn were deposited on platinized wafers in a planetary multi-wafer reactor combined with a liquid delivery system. As a direct consequence of the reactor design, we obtain high film uniformity over 6 inch wafers as well as efficiencies for the precursor incorporation as high as 40%. The composition and microstructure of the films were routinely investigated by X-ray diffraction and X-ray fluorescence analysis. Further details of the microstructure were investigated by scanning electron microscopy. The electrical properties are characterized in terms of permittivity, loss angle, leakage current and the response to DRAM pulses and characteristic values obtained for depositions at 625 degreesC include a specific capacitance of 60 fF/mum(2), a tan delta of 0.002 and leakage currents in the order of 10(-10) A/cm(2) at 1 V. The electrical properties are discussed in relation to the microstructure and stoichiometry within a wide range of parameters. (C) 2001 Elsevier Science Ltd. All rights reserved.
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Nelson Mandela Metropolitan Univ, Dept Phys, ZA-6031 Port Elizabeth, South AfricaNelson Mandela Metropolitan Univ, Dept Phys, ZA-6031 Port Elizabeth, South Africa
Pagni, O
Somhlahlo, NN
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Nelson Mandela Metropolitan Univ, Dept Phys, ZA-6031 Port Elizabeth, South AfricaNelson Mandela Metropolitan Univ, Dept Phys, ZA-6031 Port Elizabeth, South Africa
Somhlahlo, NN
Weichsel, C
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Nelson Mandela Metropolitan Univ, Dept Phys, ZA-6031 Port Elizabeth, South AfricaNelson Mandela Metropolitan Univ, Dept Phys, ZA-6031 Port Elizabeth, South Africa
Weichsel, C
Leitch, AWR
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Nelson Mandela Metropolitan Univ, Dept Phys, ZA-6031 Port Elizabeth, South AfricaNelson Mandela Metropolitan Univ, Dept Phys, ZA-6031 Port Elizabeth, South Africa
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Univ Versailles St Quentin, CNRS, Grp Etude Mat Condensee, F-92195 Meudon, France
Fac Sci Tunis, Unite Spectroscopie Raman, Tunis 2092, TunisiaUniv Versailles St Quentin, CNRS, Grp Etude Mat Condensee, F-92195 Meudon, France
Marzouki, A.
Lusson, A.
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Univ Versailles St Quentin, CNRS, Grp Etude Mat Condensee, F-92195 Meudon, FranceUniv Versailles St Quentin, CNRS, Grp Etude Mat Condensee, F-92195 Meudon, France
Lusson, A.
Jomard, F.
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Univ Versailles St Quentin, CNRS, Grp Etude Mat Condensee, F-92195 Meudon, FranceUniv Versailles St Quentin, CNRS, Grp Etude Mat Condensee, F-92195 Meudon, France
Jomard, F.
Sayari, A.
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Fac Sci Tunis, Unite Spectroscopie Raman, Tunis 2092, TunisiaUniv Versailles St Quentin, CNRS, Grp Etude Mat Condensee, F-92195 Meudon, France
Sayari, A.
Galtier, P.
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Univ Versailles St Quentin, CNRS, Grp Etude Mat Condensee, F-92195 Meudon, FranceUniv Versailles St Quentin, CNRS, Grp Etude Mat Condensee, F-92195 Meudon, France
Galtier, P.
Oueslati, M.
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Fac Sci Tunis, Unite Spectroscopie Raman, Tunis 2092, TunisiaUniv Versailles St Quentin, CNRS, Grp Etude Mat Condensee, F-92195 Meudon, France
Oueslati, M.
Sallet, V.
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Univ Versailles St Quentin, CNRS, Grp Etude Mat Condensee, F-92195 Meudon, FranceUniv Versailles St Quentin, CNRS, Grp Etude Mat Condensee, F-92195 Meudon, France