Direct observation of an equilibrium between (ButCH2)2W(CBut)(SiButPh2) and (ButCH2)W(=CHBut)2(SiButPh2) and an unusual silyl migration

被引：61

作者：

Chen, TN

Wu, ZZ

Li, LT

Sorasaenee, KR

Diminnie, JB

Pan, HJ

Guzei, IA

Rheingold, AL

Xue, ZL ^{[1
]}

机构：

[1] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

[2] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1998年 / 120卷 / 51期

关键词：

D O I：

10.1021/ja982571l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：13519 / 13520

页数：2

共 51 条

[1]

AGUERO A, 1988, NEW J CHEM, V12, P111

[2] Tungsten tris(pyrazolyl)borate cage expansion by formal insertion of an alkylidyne group into a tungsten-nitrogen bond [J].

Ahn, S ;

Mayr, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (31) :7408-7409

[3] (TRIMETHYLSILYL)METHYLIDENE AND (TRIMETHYLSILYL) METHYLIDYNE COMPOUNDS OF MOLYBDENUM AND TUNGSTEN - (ME3SICH2)3M=CSIME3 (M = MO, W) AND (ME3SICH2)3MO=CHSIME3 [J].

ANDERSEN, RA ;

CHISHOLM, MH ;

GIBSON, JF ;

REICHERT, WW ;

ROTHWELL, IP ;

WILKINSON, G .

INORGANIC CHEMISTRY, 1981, 20 (11) :3934-3936

[4]

[Anonymous], 1986, REACTIONS COORDINATE

[5] SOME ASPECTS OF SILICON-TRANSITION-METAL CHEMISTRY [J].

AYLETT, BJ .

ADVANCES IN INORGANIC CHEMISTRY, 1982, 25 :1-133

[6] SYNTHESIS AND REACTIONS OF SILYL AND GERMYL DERIVATIVES OF SCANDOCENE - STRUCTURE OF CP2SC[SI(SIME3)3](THF) [J].

CAMPION, BK ;

HEYN, RH ;

TILLEY, TD .

ORGANOMETALLICS, 1993, 12 (07) :2584-2590

[7] DIRECT OBSERVATION OF ALPHA-HYDROGEN TRANSFER FROM ALKYL TO ALKYLIDYNE LIGANDS IN (ME3CCH2)3W=CSIME3 - KINETIC AND MECHANISTIC STUDIES OF ALKYL ALKYLIDYNE EXCHANGE [J].

CAULTON, KG ;

CHISHOLM, MH ;

STREIB, WE ;

XUE, ZL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (16) :6082-6090

[8] CRYSTAL-STRUCTURE AND MOLECULAR-GEOMETRY OF W(=CCME3)(=CHCME3)(CH2CME3)(DMPE), A MONONUCLEAR TUNGSTEN(VI) COMPLEX WITH METAL-ALKYLIDYNE, METAL-ALKYLIDENE, AND METAL-ALKYL LINKAGES [J].

CHURCHILL, MR ;

YOUNGS, WJ .

INORGANIC CHEMISTRY, 1979, 18 (09) :2454-2458

[9] MULTIPLE METAL-CARBON BONDS .12. TUNGSTEN AND MOLYBDENUM NEOPENTYLIDYNE AND SOME TUNGSTEN NEOPENTYLIDENE COMPLEXES [J].

CLARK, DN ;

SCHROCK, RR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (21) :6774-6776

[10]

COLOMER E, 1981, TOP CURR CHEM, V96, P79

← 1 2 3 4 5 6 →