Rhodium-Catalyzed Alkenyl C-H Activation and Oxidative Coupling with Allylic Alcohols

被引：17
作者：
Yan, Rui [1 ,2 ]
Wang, Zhong-Xia [1 ,2 ,3 ]
机构：
[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, CAS Key Lab Soft Matter Chem, Hefei 230026, Anhui, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
[3] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 7卷 / 01期
关键词：
alkenylpyridine; allylic alcohol; C-C coupling; C-H activation; rhodium catalysis; ELECTRON-DEFICIENT ARENES; N-TYPE REACTIONS; REGIOSELECTIVE ALLYLATION; BOND ACTIVATION; ALKYLATION; ARYL; CYANATION; COMPLEXES; INDOLES; HYDRIDE;
D O I：
10.1002/ajoc.201700515
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[Cp*RhCl2](2) was demonstrated to catalyze the oxidative coupling of alkenylpyridines with allylic alcohols through alkenyl C-H activation in the presence of AgOTf and AgOAc to afford beta-alkenyl ketones and aldehydes in moderate to good yields. Allylic alcohol, 1-aryl and 1-alkyl allylic alcohols can be coupled with various alkenylpyridines. The reaction occurred at the gamma-position of allylic alcohols and the cis-beta-position of the alkenylpyridines.
引用
收藏
页码：240 / 247
页数：8
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