Biomimetic self-assembly synthesis of ZnS chain-like nanospheres with supported liquid membrane

被引：0
|
作者：
Sun, DM [1 ]
Wu, QS
Zhu, Y
Ding, YP
机构：
[1] Tongji Univ, Dept Chem, Shanghai 200092, Peoples R China
[2] Shanghai Univ, Dept Chem, Shanghai 200436, Peoples R China
来源：
ACTA CHIMICA SINICA | 2005年 / 63卷 / 16期
关键词：
supported liquid membrane; biomimetic; zinc sulfide; nano-sphere; chain-like;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel synthesis method of ZnS chain-like nanospheres by supported liquid membrane system has been investigated. The system, with o-phenanthroline as a mobile carrier, can selectively transport zinc ions to the other side of the membrane. Nucleation process was under the control of SLM template effect by directionally combining anion, local super saturation solution and the interfacial microenvironment. XRD and TEM data indicated that the crystal has cubic structure of blende with cell constant of a=0.5390 nm in the range of 250 similar to 300 nm. In addition, the morphological formation mechanism and luminescence properties of ZnS have been discussed.
引用
收藏
页码：1479 / 1482
页数：4
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