Switching the recognition ability of a photoswitchable receptor towards phosphorylated anions

被引：16

作者：

Hossain, Munshi Sahid ^{[1
]}

Rahaman, Sk. Atiur ^{[1
]}

Hatai, Joydev ^{[2
]}

Saha, Saha Monochura ^{[1
]}

Bandyopadhyay, Subhajit ^{[1
]}

机构：

[1] Indian Inst Sci Educ & Res IISER Kolkata, Dept Chem Sci, Nadia 741246, W Bengal, India

[2] Univ Duisburg Essen, Inst Organ Chem, Univ Str, D-745141 Essen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 30期

关键词：

KINASE-ACTIVITY; ATP; AZOBENZENES; SELECTIVITY; BINDING;

D O I：

10.1039/d0cc00926a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An azobenzene based photoswitchable macrocyclic receptor displays different binding affinities in its E and Z forms towards various phosphorylated coenzymes under physiological conditions with remarkable selectivity for ATP in the E-form and selectivity towards GTP in the photoisomerized Z-form. Linear discriminant analysis clearly separated the analytes using the E-form. An application of this method enabled monitoring the progress of enzymatic phosphorylation using a tyrosine kinase enzyme.

引用

收藏

页码：4172 / 4175

页数：4

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