[SiCu(H2O)W11O39]6- on glassy carbon electrode and its electrocatalytic properties

被引：0

作者：

Du, JY ^{[1
]}

Lu, GQ ^{[1
]}

Hu, CW ^{[1
]}

机构：

[1] Beijing Inst Technol, Sch Sci, Dept Chem, Beijing 100081, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2005年 / 21卷 / 05期

关键词：

transition metal substituted polyoxometalates [SiCu(H2O)W11O39](6-); multilayer assembly; cyclic voltammetry; electrocatalysis;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The electrochemical behavior of SiCuW11 heteropolyacide in acidic aqueous solution was studied. The effect of solution pH on the electrochemical behavior of SiCuW11 was discussed and the mechanism was suggested. New electrode was modified by multilayer films composed of heteropolyanion (SiCuW11) and cationic polymer poly (diallyldimethylammonium chloride). Cyclic voltammetry showed the uniform growth of the film. The modified electrodes exhibited some special electrochemical properties in the films, different from those in homogeneous aqueous solutions. The effect of pH on the redox behavior of SiCuW11 in the films was discussed in details. The multilayer film electrodes have an excellent electrocatalytic response to the reduction of BrO3- and NO2-.

引用

页码：685 / 688

页数：4

共 8 条

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