Medium-size cyclophanes, 77: Synthesis and addition of bromine to syn-[2.n]meta-cyclophan-1-enes

被引：4

作者：

Saisyo, Tatsunori ^{[1
]}

Shiino, Mikiko ^{[1
]}

Hu, Jian-yong ^{[1
]}

Yamato, Takehiko ^{[1
]}

机构：

[1] Saga Univ, Fac Sci & Engn, Dept Appl Chem, Saga 8408502, Japan

来源：

JOURNAL OF CHEMICAL RESEARCH | 2007年 / 11期

关键词：

cyclophanes; 2.n]metacyclophan-1-ene; McMurry reaction; conformation; bromination; cis-addition;

D O I：

10.3184/030823407X262445

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

McMurry cyclisation of l,n-bis(3-formyl-2-methoxyphenyl)alkanes afforded syn-dimethoxy[2.n]metacyclophan-1-enes, in which cis-addition of bromine to the bridged double bond in CH2Cl2 was observed.

引用

页码：621 / 625

页数：5

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