Orthogonal synthesis of poly(aryl ether amide) dendrons

被引：4
作者：
In, I
Kim, SY
机构：
[1] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea
[2] Korea Adv Inst Sci & Technol, Sch Mol Sci BK21, Taejon 305701, South Korea
来源：
MACROMOLECULES | 2005年 / 38卷 / 23期
关键词：
D O I：
10.1021/ma051538y
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A simple orthogonal convergent methodology for the synthesis poly(aryl ether amide) dendrons was introduced. It was found that nucleophilic aromatic substitution and amidation were chosen as orthogonal coupling reactions because each coupling reaction do not interfere with the other coupling reaction. It was observed that all poly(aryl ether amide) dendrons show enhanced solubility resulting from dendritic macromolecular structures compared with the linear or hyperbranched poly(aryl ether amides). The results show that each single orthogonal reaction produced next generation dendrons with high purity after simple precipitation.
引用
收藏
页码：9399 / 9401
页数：3
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