Selective Iron-Catalyzed Oxidation of Benzylic and Allylic Alcohols

被引：54

作者：

Join, Benoit ^{[1
]}

Moeller, Konstanze ^{[1
]}

Ziebart, Carolin ^{[1
]}

Schroeder, Kristin ^{[1
]}

Goerdes, Dirk ^{[2
]}

Thurow, Kerstin ^{[2
]}

Spannenberg, Anke ^{[1
]}

Junge, Kathrin ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

[2] Univ Rostock, Ctr Life Sci Automat CELISCA, D-18119 Rostock, Germany

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2011年 / 353卷 / 16期

关键词：

alcohols; catalysis; hydrogen peroxide; iron; oxidation; ASYMMETRIC TRANSFER HYDROGENATION; SATURATED-HYDROCARBONS; SULFIDE OXIDATION; AEROBIC OXIDATION; EFFICIENT; PEROXIDE; EPOXIDATION; OLEFINS; HYDROSILYLATION; COMPLEXES;

D O I：

10.1002/adsc.201100210

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A convenient and selective oxidation of alcohols with hydrogen peroxide to give aldehydes and ketones has been developed. Using in situ generated iron chloride complexes [Fe(L3)2Cln] [n=01, L3 =6-(N-phenylbenzimidazoyl)-2-pyridinecarboxylic acid], aldehydes and ketones were obtained in good yield and excellent selectivity after a short reaction time at room temperature.

引用

页码：3023 / 3030

页数：8

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