Hydrophobic and metal coordination interacted architecture based on p-tert-butylthiacalix[4]arene-potassium complex and its vapor absorption capability

被引：15

作者：

Yamada, Manabu ^{[1
]}

Kondo, Yoshihiko ^{[1
]}

Iki, Nobuhiko ^{[2
]}

Kabuto, Chizuko ^{[3
]}

Hamada, Fumio ^{[1
]}

机构：

[1] Akita Univ, Fac Engn & Resource Sci, Dept Mat Proc Engn & Appl Chem Environm, Tegatagakuen, Akita 0108502, Japan

[2] Tohoku Univ, Grad Sch Environm Studies, Dept Environm Studies, Aoba Ku, Sendai, Miyagi 9808578, Japan

[3] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan

来源：

TETRAHEDRON LETTERS | 2008年 / 49卷 / 24期

关键词：

D O I：

10.1016/j.tetlet.2008.04.057

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Single-crystal X-ray diffraction studies of [K(1.3H)]center dot 2MeOH complex obtained from p-tert-butylthiacalix[4]arene (1.4H) with KH, which shows two dimer formations. One of the dimers is formed by a hydrophobic interaction between each tert-butyl group of 1.3H and the cavity of another 1.3H in the crystalline state. The other dimer made metal coordination S center dot center dot center dot K center dot center dot center dot(O,S,O) between neighboring 1.3H and potassium ion. In the overall structure, this complex indicates non-porous structure and the adsorption capabilities toward gaseous organic molecules. (c) 2008 Elsevier Ltd. All rights reserved.

引用

页码：3906 / 3911

页数：6

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