An aluminum porphyrin complex with high activity and selectivity for cyclic carbonate synthesis

被引：152

作者：

Qin, Yusheng ^{[1
]}

Guo, Hongchen ^{[1
]}

Sheng, Xingfeng ^{[1
,2
]}

Wang, Xianhong ^{[1
]}

Wang, Fosong ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, Key Lab Polymer Ecomat, Changchun 130022, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100039, Peoples R China

来源：

GREEN CHEMISTRY | 2015年 / 17卷 / 05期

基金：

中国国家自然科学基金;

关键词：

EFFICIENT CATALYSTS; CHEMICAL FIXATION; COUPLING REACTION; DIOXIDE FIXATION; PROPYLENE-OXIDE; CO2; EPOXIDES; COPOLYMERIZATION; POLYMERIZATION; CYCLOADDITION;

D O I：

10.1039/c4gc02310b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An aluminum porphyrin complex with a quaternary ammonium salt cocatalyst exhibits high activity (i.e., a turnover frequency as high as 1.85 x 10(5) h(-1)) and selectivity (>99%) for cyclic carbonates synthesis from CO2 and epoxides; the catalyst can be reused at least 4 times with only a slight loss in activity.

引用

页码：2853 / 2858

页数：6

共 44 条

[1] Highly efficient chemical fixation of carbon dioxide catalyzed by high-valent tetraphenylporphyrinatotin(IV) triflate
Ahmadi, Fatemeh
Tangestaninejad, Shahram
Moghadam, Majid
Mirkhani, Valiollah
Mohammadpoor-Baltork, Iraj
Khosropour, Ahmad Reza
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (09) : 1489 - 1493
[2] Cobaltoporphyrin-Catalyzed CO2/Epoxide Copolymerization: Selectivity Control by Molecular Design
Anderson, Carly E.
Vagin, Sergei I.
Xia, Wei
Jin, Hanpeng
Rieger, Bernhard
[J]. MACROMOLECULES, 2012, 45 (17) : 6840 - 6849
[3] Utilisation of CO2 as a chemical feedstock:: opportunities and challenges
Aresta, Michele
Dibenedetto, Angela
[J]. DALTON TRANSACTIONS, 2007, (28) : 2975 - 2992
[4] Carbon Dioxide Fixation by Cycloaddition with Epoxides, Catalyzed by Biomimetic Metalloporphyrins
Bai, Dongsheng
Duan, Shuhui
Hai, Long
Jing, Huanwang
[J]. CHEMCATCHEM, 2012, 4 (11) : 1752 - 1758
[5] Bifunctional Metalloporphyrins-Catalyzed Coupling Reaction of Epoxides and CO2 to Cyclic Carbonates
Bai Dongsheng
Wang Xiaoxuan
Song Yingying
Li Bo
Zhang Lilong
Yan Peng
Jing Huanwang
[J]. CHINESE JOURNAL OF CATALYSIS, 2010, 31 (02) : 176 - 180
[6] The Influence of the Metal (Al, Cr, and Co) and the Substituents of the Porphyrin in Controlling the Reactions Involved in the Copolymerization of Propylene Oxide and Carbon Dioxide by Porphyrin Metal(III) Complexes. 1. Aluminum Chemistry
Chatterjee, Chandrani
Chisholm, Malcolm H.
[J]. INORGANIC CHEMISTRY, 2011, 50 (10) : 4481 - 4492
[7] Binding of propylene oxide to porphyrin- and salen-M(III) cations, where M = Al, Ga, Cr, and Co
Chen, P
Chisholm, MH
Gallucci, JC
Zhang, XY
Zhou, ZP
[J]. INORGANIC CHEMISTRY, 2005, 44 (08) : 2588 - 2595
[8] Reactive applications of cyclic alkylene carbonates
Clements, JH
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2003, 42 (04) : 663 - 674
[9] Salen-Complex-Mediated Formation of Cyclic Carbonates by Cycloaddition of CO2 to Epoxides
Decortes, Antonello
Castilla, Ana M.
Kleij, Arjan W.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (51) : 9822 - 9837
[10] Reactivity of osmium(VI) nitrides with the azide ion. A new synthetic route to osmium(II) polypyridyl complexes
Demadis, KD
Meyer, TJ
White, PS
[J]. INORGANIC CHEMISTRY, 1998, 37 (14) : 3610 - 3619

← 1 2 3 4 5 →