Synthesis and Chemosensory Properties of New Cyanosubstituted 2,2'-Bipyridine Derivatives

被引：6
作者：
Ievlev, Mikhail Yu [1 ]
Mayorov, Nikita S. [1 ]
Bardasov, Ivan N. [1 ]
Sorokin, Saveliy P. [1 ]
Belikov, Mikhail Yu [1 ]
Ershov, Oleg, V [1 ]
机构：
[1] Ulyanov Chuvash State Univ, Moskovsky Pr 15, Cheboksary, Russia
来源：
JOURNAL OF FLUORESCENCE | 2022年 / 32卷 / 06期
关键词：
2; 2'-Bipyridine; Nitriles; Fluorescence; Chemosensors; Metal sensing; 2,2'-BIPYRIDINE; BIPYRIDINE; LIGANDS; PHOTOPHYSICS; COMPLEXES; ZN(II); SENSOR;
D O I：
10.1007/s10895-022-03027-9
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
A series of novel 6-oxo-1,6-dihydro-[2,2'-bipyridine]-5-carbonitriles has been synthesized and characterized. Their photophysical properties in DMSO solution and aqueous medium as well as fluorescence response to the presence of metal ions have been investigated. The obtained 4-(4-methoxyphenyl)-6-oxo-1,6-dihydro-[2,2'-bipyridine]-5-carbonitrile has been shown as a selective fluorescent "turn-ON" probe for Cd2+ ions with LoD 0.359 mu M, 1:1 metal-ligand ratio and binding constant of 5.2 x 10(4) M-1.
引用
收藏
页码：2333 / 2342
页数：10
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