Studies on the silylation reaction of α,β-epoxy esters synthesized by Darzen's condensation reaction

被引:2
作者
Bolourtchian, M
Mamaghani, M
Badrian, A
机构
[1] Guilan Univ, Fac Sci, Dept Chem, Rasht, Iran
[2] Chem & Chem Engn Res Ctr Iran, Tehran, Iran
关键词
D O I
10.1080/714040968
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Me3SiCl/Mg in HMPA was used forsilylation of alpha,beta-epoxy esters resulting in the corresponding beta-silylated esters in a one pot reaction with reasonable yields.
引用
收藏
页码:2545 / 2550
页数:6
相关论文
共 14 条
[1]   NEW METHODS FOR CREATION OF SILICON-CARBON BOND FROM CHLOROSILANES .14. SILYLATION OF ALPHA ETHYLENIC AMIDES [J].
BOLOURTCHIAN, M ;
BOURGEOI.P ;
CALAS, R ;
DUNOGUES, J ;
DUFFAUT, N .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 43 (01) :139-+
[2]   Synthesis of α, γ-disilylated amines from β-silylated imines [J].
Bolourtchian, M ;
Badrian, A .
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1999, 152 :129-134
[3]   NEW METHODS FOR FORMATION OF SILICON-CARBON BOND FROM CHLOROSILATES .1. TESTS FOR SILYLATION OF ALPHA ETHYLENIC NITRILES [J].
BOLOURTCHIAN, M ;
CALAS, R ;
DUNOGUES, J ;
DUFFAUT, N .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1971, 33 (03) :303-+
[4]  
BOLOURTCHIAN M, 1990, J SCI I R IRAN, V3, P177
[5]  
BOLOURTCHIAN M, 1990, J SCI I R IRAN, V4, P57
[6]   ACTION OF TRIMETHYLCHLOROSILANE ON ALPHA IONONE AND BETA IONONE IN PRESENCE OF MAGNESIUM [J].
CALAS, R ;
BOLOURTC.M ;
DUFFAUT, N ;
DUNOGUES, J .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 34 (02) :269-&
[7]   NEW METHOD FOR CREATING SILICON-CARBON BOND FROM CHLOROSILANES .8. C-SILYLATION OF ALPHA-ETHYLENIC ALDEHYDES AND KETONES [J].
CALAS, R ;
DUNOGUES, J ;
BOLOURTC.M .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1971, 26 (02) :195-&
[8]  
Colvin E. W., 1988, SILICON REAGENTS ORG
[9]   C-SILYLATION AND REDUCTIVE DUPLICATION OBSERVED DURING ACTION OF ME3SICL-MG-HMPT ON CARBONYLATED ALPHA-ETHYLENIC COMPOUNDS - APPLICATION TO PREPARATION OF D'-EPSILON DIKETONES FROM ALPHA-ETHYLENIC KETONES [J].
DUNOGUES, J ;
CALAS, R ;
BOLOURTC.M ;
BIRAN, C ;
DUFFAUT, N .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 57 (01) :55-69
[10]  
DUNOGUES J, 1972, J ORGANOMET CHEM, V34, P157