Synthesis and characterization of novel covalently linked - Fullerene-porphyrin compouds

被引：0

作者：

Yang, SG ^{[1
]}

Liu, JY ^{[1
]}

Wu, ZY ^{[1
]}

Tian, L ^{[1
]}

Fan, SH ^{[1
]}

Zhan, MX ^{[1
]}

机构：

[1] Xiamen Univ, Dept Chem, Xiamen 361005, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2005年 / 26卷 / 07期

关键词：

fullerene; fulleropyrrolidine; porphyrin; metal porphyrin;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In order to construct a donor-acceptor system with efficient electron transfer, a novel covalently linked fullerene-porphyrin ligand (H2P-C-60) was synthesized by 1, 3-dipolar cycloaddition reaction of C-60, sarcosine and H2P-CHO, and it's zinc derivative was prepared by metalation of H2P-C-60 and zinc acetate. The two new fullerene-porphyrin compounds were characterized by means of elemental analysis, IR, electronic spectra, ESI-MS and H-1 NMR. They are also predicted to have good optical and electrical properties.

引用

页码：1202 / 1205

页数：4

共 19 条

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