Changes of microstructure and magnetic properties of Nd-Fe-B sintered magnets by doping Al-Cu

被引:42
作者
Ni, Junjie [1 ,2 ]
Ma, Tianyu [1 ]
Yan, Mi [1 ]
机构
[1] Zhejiang Univ, Dept Mat Sci & Engn, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China
[2] Liaocheng Univ, Coll Mat Sci & Engn, Liaocheng 252000, Peoples R China
基金
中国国家自然科学基金;
关键词
Nd-Fe-B magnet; Magnetic property; Microstructure; Annealing; CORROSION-RESISTANCE; INTERGRANULAR ADDITION; PERMANENT-MAGNETS; COERCIVITY; IMPROVEMENT; BEHAVIOR; NDFEB; HEAT; DY;
D O I
10.1016/j.jmmm.2011.05.029
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The microstructural and magnetic properties of Al(100-x)Cu(x) (15at% <= x <= 45 at%) doped Nd-Fe-B magnets were studied. The distribution and alloying effects of Cu or Al on the intergranular microstructure were investigated by thermodynamic analysis, differential scanning calorimetery and microscopy techniques. It was observed that when the Cu content of Al(100x)Cu(x) exceeds to 25 at%, the (Pr, Nd)Cu and CuAl(2) phases form in these magnets. The formation of (Pr, Nd)Cu phase depends on the negative formation enthalpy of (Pr, Nd)Cu and the exclusive distribution of Cu in the intergranular regions. The eutectic reaction between (Pr, Nd)Cu phase and (Pr, Nd) occurs at 480 degrees C, which forms the liquid phase that dissolves the (Pr, Nd)(2)Fe(14)B surface irregularities and thus increases the quantities of (Pr, Nd)-rich phase at the grain boundaries. These changes benefit the grain boundary microstructure, especially the distribution of (Pr, Nd)-rich phase, which effectively improves the intrinsic coercivity (i)H(c) due to the decreases of exchange coupling between the (Pr, Nd)(2)Fe(14)B grains. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:2549 / 2553
页数:5
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