Fluorescent metal-organic framework for selective sensing of nitroaromatic explosives

被引:485
作者
Gole, Bappaditya [1 ]
Bar, Arun Kumar [1 ]
Mukherjee, Partha Sarathi [1 ]
机构
[1] Indian Inst Sci, Dept Inorgan & Phys Chem, Bangalore 560012, Karnataka, India
关键词
CHEMICAL SENSORS; VAPOR DETECTION; POLYMER-FILMS; TNT; SENSITIVITY;
D O I
10.1039/c1cc15594f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Highly luminescent micrometre-sized fine particles of a Zn(II) metal-organic framework (MOF) of a new pi-electron rich tricarboxylate dispersed in ethanol is demonstrated as a selective sensory material for the detection of nitroaromatic explosives via a fluorescence quenching mechanism.
引用
收藏
页码:12137 / 12139
页数:3
相关论文
共 31 条
[11]  
2-8
[12]   Conjugated polymer-based chemical sensors [J].
McQuade, DT ;
Pullen, AE ;
Swager, TM .
CHEMICAL REVIEWS, 2000, 100 (07) :2537-2574
[13]   Instrumentation for trace detection of high explosives [J].
Moore, DS .
REVIEW OF SCIENTIFIC INSTRUMENTS, 2004, 75 (08) :2499-2512
[14]   Hydrogen storage in metal-organic frameworks [J].
Murray, Leslie J. ;
Dinca, Mircea ;
Long, Jeffrey R. .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1294-1314
[15]   Photoluminescent coordination polymers of d10 metals with 4,4′-dipyridylsulfide (dps) [J].
Muthu, S ;
Ni, Z ;
Vittal, JJ .
INORGANICA CHIMICA ACTA, 2005, 358 (03) :595-605
[16]   RPM-1: A recyclable nanoporous material suitable for ship-in-bottle synthesis and large hydrocarbon sorption [J].
Pan, L ;
Liu, HM ;
Lei, XG ;
Huang, XY ;
Olson, DH ;
Turro, NJ ;
Li, J .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (05) :542-+
[17]   New Microporous Metal-Organic Framework Demonstrating Unique Selectivity for Detection of High Explosives and Aromatic Compounds [J].
Pramanik, Sanhita ;
Zheng, Chong ;
Zhang, Xiao ;
Emge, Thomas J. ;
Li, Jing .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (12) :4153-4155
[18]   Sensitivity gains in chemosensing by lasing action in organic polymers [J].
Rose, A ;
Zhu, ZG ;
Madigan, CF ;
Swager, TM ;
Bulovic, V .
NATURE, 2005, 434 (7035) :876-879
[19]   The molecular wire approach to sensory signal amplification [J].
Swager, TM .
ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (05) :201-207
[20]   Chemical sensors based on amplifying fluorescent conjugated polymers [J].
Thomas, Samuel W., III ;
Joly, Guy D. ;
Swager, Timothy M. .
CHEMICAL REVIEWS, 2007, 107 (04) :1339-1386