Facile Synthesis of 5-Substituted 1H-Tetrazoles Catalyzed by Tetrabutylammonium Hydrogen Sulfate in Water

被引：15
|
作者：
Wang, Zengtao [1 ,2 ]
Liu, Zhiguo [3 ]
Cheon, Seung Hoon [1 ,2 ]
机构：
[1] Chonnam Natl Univ, Coll Pharm, Kwangju 500757, South Korea
[2] Chonnam Natl Univ, Res Inst Drug Dev, Kwangju 500757, South Korea
[3] Wenzhou Med Coll, Sch Pharm, Wenzhou 325035, Zhejiang, Peoples R China
来源：
BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2015年 / 36卷 / 01期
关键词：
3+2] Cycloaddition; Nitrile; Sodium azide; Tetrabutylammonium hydrogen sulfate; Tetrazoles; TRIMETHYLSILYL AZIDE; EFFICIENT SYNTHESIS; 3+2 CYCLOADDITION; NITRILES; TETRAZOLES; CHEMISTRY; ACID; CHLORIDES; AGENTS; AZOLE;
D O I：
10.1002/bkcs.10045
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Facile synthesis of 5-substituted 1H-tetrazoles was achieved by treating nitriles with NaN3 in water or toluene in the presence of tetrabutylammoniumhydrogen sulfate (TBAHS). The reaction could be carried out in water as well as in toluene. The procedure is environment-friendly, practical, and provides excellent yield of tetrazoles.
引用
收藏
页码：198 / 202
页数：5
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