Factors affecting early-age hydration of ordinary Portland cement studied by NMR: Fineness, water-to-cement ratio and curing temperature

被引:31
作者
Alesiani, M. [1 ]
Pirazzoli, I. [1 ]
Maraviglia, B. [1 ,2 ]
机构
[1] Univ Roma La Sapienza, Ctr Ric Sviluppo, Ist Nazl Fis Mat, Dept Phys,SOFT, I-00185 Rome, Italy
[2] Enrico Fermi Ctr, Rome, Italy
关键词
D O I
10.1007/s00723-007-0019-y
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
The aim of the present study was to apply nuclear magnetic resonance (NMR) relaxation measurements for understanding the microstructure evolution of cement paste during hydration. Ordinary Portland cement powder was mixed with double-distilled water, and hydration process was analyzed via H-1 proton NMR spin-spin relaxation time. In order to induce strong modification of the rate of hydration, water-to-cement ratio, curing temperature and cement fineness were varied. The evolution of the NMR spin-spin relaxation time, T-2, of hydrating water versus the hydration time was monitored from the very first few minutes after the mixing up to several hours.
引用
收藏
页码:385 / 394
页数:10
相关论文
共 21 条
  • [1] BARBIC L, 1979, CIMENT BETONS PLATRE, V718, P172
  • [2] Effects of cement particle size distribution on performance properties of Portland cement-based materials
    Bentz, DP
    Garboczi, EJ
    Haecker, CJ
    Jensen, OM
    [J]. CEMENT AND CONCRETE RESEARCH, 1999, 29 (10) : 1663 - 1671
  • [3] Magnetic resonance studies of cement based materials in inhomogeneous magnetic fields
    Boguszynska, J
    Brown, MCA
    McDonald, PJ
    Mitchell, J
    Mulheron, M
    Tritt-Goc, J
    Verganelakis, DA
    [J]. CEMENT AND CONCRETE RESEARCH, 2005, 35 (10) : 2033 - 2040
  • [4] A broad line NMR and MRI study of water and water transport in Portland cement pastes
    Bohris, AJ
    Goerke, U
    McDonald, PJ
    Mulheron, M
    Newling, B
    Le Page, B
    [J]. MAGNETIC RESONANCE IMAGING, 1998, 16 (5-6) : 455 - 461
  • [5] EFFECTS OF DIFFUSION ON FREE PRECESSION IN NUCLEAR MAGNETIC RESONANCE EXPERIMENTS
    CARR, HY
    PURCELL, EM
    [J]. PHYSICAL REVIEW, 1954, 94 (03): : 630 - 638
  • [6] Effect of temperature on the hydration of the main clinker phases in Portland cements: Part II, blended cements
    Escalante-Garcia, JI
    Sharp, JH
    [J]. CEMENT AND CONCRETE RESEARCH, 1998, 28 (09) : 1259 - 1274
  • [7] NMR diffusion and relaxation studies during cement hydration -: A non-destructive approach for clarification of the mechanism of internal post curing of cementitious materials
    Friedemann, Karen
    Stallmach, Frank
    Karger, Jorg
    [J]. CEMENT AND CONCRETE RESEARCH, 2006, 36 (05) : 817 - 826
  • [8] COMPOSITIONAL MODEL FOR CALCIUM SILICATE HYDRATE (C-S-H) GELS, THEIR SOLUBILITIES, AND FREE-ENERGIES OF FORMATION
    GLASSER, FP
    LACHOWSKI, EE
    MACPHEE, DE
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1987, 70 (07) : 481 - 485
  • [9] Greener J, 2000, J AM CERAM SOC, V83, P623
  • [10] Monitoring of cement hydration by broadband time-domain-reflectometry dielectric spectroscopy
    Hager, NE
    Domszy, RC
    [J]. JOURNAL OF APPLIED PHYSICS, 2004, 96 (09) : 5117 - 5128