Potassium fluoride on alumina: Synthesis of O-aryl N,N-dimethylthiocarbamates and their rearrangement into S-aryl N,N-dimethylthiocarbamates under microwave irradiation

被引：27
作者：
Villemin, D
Hachemi, M
Lalaoui, M
机构：
[1] Ecl. Natl. Sup. d'Ing. de Caen, I.S.M.R.A., Grp. Catalyse et Modélisation
来源：
SYNTHETIC COMMUNICATIONS | 1996年 / 26卷 / 13期
关键词：
D O I：
10.1080/00397919608004558
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of O-aryl N,N-dimethyl thiocarbamates have been prepared by the reaction of dimethylthiocarbamoyl chloride with phenols absorbed on potassium fluoride on alumina. The rearrangement of O-aryl N,N-dimethylthiocarbamate into S-aryl N,N-dimethyl thiocarbamate under microwave irradiation was also studied. The use of conductive support like graphite or silicon carbide allow these rearrangements although the O-aryl N,N-dimethylthiocarbamates have very low dielectric lost.
引用
收藏
页码：2461 / 2471
页数：11
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