Selective Hg(II) Sensing with Improved Stokes Shift by Coupling the Internal Charge Transfer Process to Excitation Energy Transfer

被引:120
作者
Atilgan, Serdar [1 ]
Ozdemir, Tugba [2 ]
Akkaya, Engin U. [2 ,3 ]
机构
[1] Suleyman Demirel Univ, Fac Arts & Sci, TR-32200 Isparta, Turkey
[2] Bilkent Univ, UNAM Inst Mat Sci & Nanotechnol, TR-06800 Ankara, Turkey
[3] Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey
关键词
FLUORESCENT; MODULATION; PRINCIPLE; LOGIC; PROOF;
D O I
10.1021/ol1019426
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Versatile chemistry of the Bodipy chromophore allows modular assembly of an excitation energy donor, acceptor, and a cation selective ligand in just a couple of steps. The new approach should be applicable in other designs which target molecular sensors with large Stokes shifts and red to near IR emission.
引用
收藏
页码:4792 / 4795
页数:4
相关论文
共 29 条
  • [1] A sensitive and selective ratiometric near IR fluorescent probe for zinc ions based on the distyryl-bodipy fluorophore
    Atilgan, Serdar
    Ozdemir, Tugba
    Akkaya, Engin U.
    [J]. ORGANIC LETTERS, 2008, 10 (18) : 4065 - 4067
  • [2] Water soluble distyryl-boradiazaindacenes as efficient photosensitizers for photodynamic therapy
    Atilgan, Serdar
    Ekmekci, Zeynep
    Dogan, A. Lale
    Guc, Dicle
    Akkaya, Engin U.
    [J]. CHEMICAL COMMUNICATIONS, 2006, (42) : 4398 - 4400
  • [3] A near IR di-styryl BODIPY-based ratiometric fluorescent chemosensor for Hg(II)
    Atilgan, Serdar
    Kutuk, Ilker
    Ozdemir, Tugba
    [J]. TETRAHEDRON LETTERS, 2010, 51 (06) : 892 - 894
  • [4] ION-RESPONSIVE FLUORESCENT COMPOUNDS .2. CATION-STEERED INTRAMOLECULAR CHARGE-TRANSFER IN A CROWNED MEROCYANINE
    BOURSON, J
    VALEUR, B
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (09) : 3871 - 3876
  • [5] Selective Manipulation of ICT and PET Processes in Styryl-Bodipy Derivatives: Applications in Molecular Logic and Fluorescence Sensing of Metal Ions
    Bozdemir, O. Altan
    Guliyev, Ruslan
    Buyukcakir, Onur
    Selcuk, Sencer
    Kolemen, Safacan
    Gulseren, Gulcihan
    Nalbantoglu, Tugrul
    Boyaci, Hande
    Akkaya, Engin U.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (23) : 8029 - 8036
  • [6] Reaction-Based Sensing of Fluoride Ions Using Built-in Triggers for Intramolecular Charge Transfer and Photoinduced Electron Transfer
    Bozdemir, O. Altan
    Sozmen, Fazli
    Buyukcakir, Onur
    Guliyev, Ruslan
    Cakmak, Yusuf
    Akkaya, Engin U.
    [J]. ORGANIC LETTERS, 2010, 12 (07) : 1400 - 1403
  • [7] Tetrastyryl-Bodipy Dyes: Convenient Synthesis and Characterization of Elusive Near IR Fluorophores
    Buyukcakir, Onur
    Bozdemir, O. Altan
    Kolemen, Safacan
    Erbas, Sundus
    Akkaya, Engin U.
    [J]. ORGANIC LETTERS, 2009, 11 (20) : 4644 - 4647
  • [8] Ion sensing coupled to resonance energy transfer: A highly selective and sensitive ratiometric fluorescent chemosensor for Ag(I) by a modular approach
    Coskun, A
    Akkaya, EU
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (30) : 10464 - 10465
  • [9] Signal ratio amplification via modulation of resonance energy transfer: Proof of principle in an emission ratiometric Hg(II) sensor
    Coskun, Ali
    Akkaya, Engin U.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (45) : 14474 - 14475
  • [10] de Silva AP, 2000, J AM CHEM SOC, V122, P3965