Selective Hg(II) Sensing with Improved Stokes Shift by Coupling the Internal Charge Transfer Process to Excitation Energy Transfer

被引:122
作者
Atilgan, Serdar [1 ]
Ozdemir, Tugba [2 ]
Akkaya, Engin U. [2 ,3 ]
机构
[1] Suleyman Demirel Univ, Fac Arts & Sci, TR-32200 Isparta, Turkey
[2] Bilkent Univ, UNAM Inst Mat Sci & Nanotechnol, TR-06800 Ankara, Turkey
[3] Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey
关键词
FLUORESCENT; MODULATION; PRINCIPLE; LOGIC; PROOF;
D O I
10.1021/ol1019426
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Versatile chemistry of the Bodipy chromophore allows modular assembly of an excitation energy donor, acceptor, and a cation selective ligand in just a couple of steps. The new approach should be applicable in other designs which target molecular sensors with large Stokes shifts and red to near IR emission.
引用
收藏
页码:4792 / 4795
页数:4
相关论文
共 29 条
[1]   A sensitive and selective ratiometric near IR fluorescent probe for zinc ions based on the distyryl-bodipy fluorophore [J].
Atilgan, Serdar ;
Ozdemir, Tugba ;
Akkaya, Engin U. .
ORGANIC LETTERS, 2008, 10 (18) :4065-4067
[2]   Water soluble distyryl-boradiazaindacenes as efficient photosensitizers for photodynamic therapy [J].
Atilgan, Serdar ;
Ekmekci, Zeynep ;
Dogan, A. Lale ;
Guc, Dicle ;
Akkaya, Engin U. .
CHEMICAL COMMUNICATIONS, 2006, (42) :4398-4400
[3]   A near IR di-styryl BODIPY-based ratiometric fluorescent chemosensor for Hg(II) [J].
Atilgan, Serdar ;
Kutuk, Ilker ;
Ozdemir, Tugba .
TETRAHEDRON LETTERS, 2010, 51 (06) :892-894
[4]   ION-RESPONSIVE FLUORESCENT COMPOUNDS .2. CATION-STEERED INTRAMOLECULAR CHARGE-TRANSFER IN A CROWNED MEROCYANINE [J].
BOURSON, J ;
VALEUR, B .
JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (09) :3871-3876
[5]   Selective Manipulation of ICT and PET Processes in Styryl-Bodipy Derivatives: Applications in Molecular Logic and Fluorescence Sensing of Metal Ions [J].
Bozdemir, O. Altan ;
Guliyev, Ruslan ;
Buyukcakir, Onur ;
Selcuk, Sencer ;
Kolemen, Safacan ;
Gulseren, Gulcihan ;
Nalbantoglu, Tugrul ;
Boyaci, Hande ;
Akkaya, Engin U. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (23) :8029-8036
[6]   Reaction-Based Sensing of Fluoride Ions Using Built-in Triggers for Intramolecular Charge Transfer and Photoinduced Electron Transfer [J].
Bozdemir, O. Altan ;
Sozmen, Fazli ;
Buyukcakir, Onur ;
Guliyev, Ruslan ;
Cakmak, Yusuf ;
Akkaya, Engin U. .
ORGANIC LETTERS, 2010, 12 (07) :1400-1403
[7]   Tetrastyryl-Bodipy Dyes: Convenient Synthesis and Characterization of Elusive Near IR Fluorophores [J].
Buyukcakir, Onur ;
Bozdemir, O. Altan ;
Kolemen, Safacan ;
Erbas, Sundus ;
Akkaya, Engin U. .
ORGANIC LETTERS, 2009, 11 (20) :4644-4647
[8]   Ion sensing coupled to resonance energy transfer: A highly selective and sensitive ratiometric fluorescent chemosensor for Ag(I) by a modular approach [J].
Coskun, A ;
Akkaya, EU .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (30) :10464-10465
[9]   Signal ratio amplification via modulation of resonance energy transfer: Proof of principle in an emission ratiometric Hg(II) sensor [J].
Coskun, Ali ;
Akkaya, Engin U. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (45) :14474-14475
[10]  
de Silva AP, 2000, J AM CHEM SOC, V122, P3965