π-Conjugated Polymers Consisting of Isothianaphthene and Dialkoxy-p-phenylene Units: Synthesis, Self-Assembly, and Chemical and Physical Properties

被引：17

作者：

Yamamoto, Takakazu ^{[1
]}

Usui, Motoaki ^{[1
]}

Ootsuka, Haruki ^{[1
]}

Iijima, Takayuki ^{[1
]}

Fukumoto, Hiroki ^{[1
]}

Sakai, Yoshimasa ^{[2
]}

Aramaki, Shinji ^{[2
]}

Yamamoto, Hiroshi M. ^{[3
]}

Yagi, Takehiko ^{[4
]}

Tajima, Hiroyuki ^{[4
]}

Okada, Taku ^{[4
]}

Fukuda, Takashi ^{[5
]}

Emoto, Akira ^{[5
]}

Ushijima, Hirobumi ^{[5
]}

Hasegawa, Miki ^{[6
]}

Ohtsu, Hideki ^{[6
]}

机构：

[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

[2] Mitsubishi Chem Grp Sci & Technol Res Ctr Inc, Aoba Ku, Yokohama, Kanagawa 2278502, Japan

[3] RIKEN, Wako, Saitama 3510198, Japan

[4] Univ Tokyo, Inst Solid State Phys, Kashiwa, Chiba 2778581, Japan

[5] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan

[6] Aoyama Gakuin Univ, Coll Sci & Engn, Dept Chem & Biol Sci, Kanagawa 2298558, Japan

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2010年 / 211卷 / 19期

关键词：

conducting polymers; conjugated polymers; isothianaphthene; polyaromatics; self-assembly; TAIL-TYPE POLY(3-HEXYLTHIOPHENE-2,5-DIYL); OPTICAL-PROPERTIES; MOLECULAR ALIGNMENT; ELECTROCHEMICAL PROPERTIES; LIQUID-CRYSTALLINE; SOLID STRUCTURE; FILMS; THIOPHENE; CONDUCTIVITY; OLIGOMERS;

D O I：

10.1002/macp.201000246

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A series of pi-conjugated alternating copolymers consisting of Th-ITN-Th and p-C6H2(OR)(2) units were synthesized. XRD indicated that the copolymers assume an interdigitation packing mode, and UV-Vis spectra revealed a strong tendency for self-assembly. Upon molecular assembly of the copolymer, the UV-Vis absorption shifted by about 100 nm to a longer wavelength from that of the single molecule. The copolymers underwent electrochemical oxidation (or p-doping) and reduction (or n-doping) at 0.2 and -2.0 V versus Ag+/Ag, respectively. A p-doped copolymer film showed an electrical conductivity of 182 S.cm(-1), and the temperature dependence of electrical conductivity was measured. The copolymer showed piezochromism and served as a p-channel material for a field-effect transistor.

引用

页码：2138 / 2147

页数：10

共 84 条

[11]

DAHLENKAMP T, 1994, MACROMOL CHEM PHYS, V195, P1933

[12]

Fichou D., 1999, HDB OLIGO AND POLYTH

[13] REGIODEFINED SUBSTITUTED POLY(2,5-THIENYLENE)S [J].

GALLAZZI, MC ;

CASTELLANI, L ;

MARIN, RA ;

ZERBI, G .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1993, 31 (13) :3339-3349

[14]

GEBEYEHU D, 2002, SYNTHETIC MET, P279

[15] CRYSTALLOGRAPHIC STUDY OF POLYMERS EXHIBITING SIDE-CHAIN CRYSTALLIZATION [J].

HSIEH, HWS ;

POST, B ;

MORAWETZ, H .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1976, 14 (07) :1241-1255

[16] Synthesis of aza-analogues of poly(isothianaphthene) [J].

Huskic, M ;

Vanderzande, D ;

Gelan, J .

SYNTHETIC METALS, 1999, 99 (02) :143-147

[17] Hopping transport in conductive heterocyclic oligomers: Reorganization energies and substituent effects [J].

Hutchison, GR ;

Ratner, MA ;

Marks, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (07) :2339-2350

[18] Main-chain-type 8-quinolinol polymers: Synthesis, optical properties, and complex formation with metals [J].

Iijima, Takayuki ;

Kuroda, Shin-ichi ;

Yamamoto, Takakazu .

MACROMOLECULES, 2008, 41 (05) :1654-1662

[19] SYNTHESIS AND CHARACTERISTIC PROPERTIES OF POLY(NAPHTHO[2,3-C]THIOPHENE) AS A SERIES OF FUSED-RING CONDUCTING POLYMERS ANALOGOUS TO POLY(ISOTHIANAPHTHENE) [J].

IKENOUE, Y .

SYNTHETIC METALS, 1990, 35 (03) :263-270

[20] CONFORMATIONAL-CHANGES OF POLY(3-ALKYLTHIOPHENE)S WITH TEMPERATURE AND PRESSURE [J].

IWASAKI, K ;

FUJIMOTO, H ;

MATSUZAKI, S .

SYNTHETIC METALS, 1994, 63 (02) :101-108

← 1 2 3 4 5 6 7 8 9 →