Synthesis of a photocrosslinkable hyperbranched polyester containing methacryloyl groups by the reaction of 1,4-bis(chloromethyl)benzene with 1,3,5-benzenetricarboxylic acid followed by reaction with methacrylic acid

被引：2
|
作者：
Maruyama, Ken [1 ]
Hirabayashi, Toshiaki [1 ]
Kudo, Hiroto [1 ]
Nishikubo, Tadatomi [1 ]
机构：
[1] Kanagawa Univ, Dept Mat & Life Chem, Fac Engn, Kanagawa Ku, Yokohama, Kanagawa 2218686, Japan
来源：
POLYMER JOURNAL | 2010年 / 42卷 / 10期
关键词：
DBU; hyperbranched polymer; photoradical polymerization; polyester; POLYMERIZATION; BIS(OXETANE)S; POLYADDITION; POLYIMIDES;
D O I：
10.1038/pj.2010.74
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The synthesis and photo-polymerization of hyperbranched polyesters (HBPEs) containing terminal methacryloyl groups (HBPE-MA) were examined. Polycondensations of 1,4-bis(chloromethyl) benzene with 1,3,5-benzenetricarboxylic acid using 1, 8-diazabicyclo[5.4.0] undec-7-ene as a base were performed to give the soluble HBPEs in satisfactorily high yields. Furthermore, HBPE-MA was synthesized by the reaction of HBPE with methacrylic acid. The photo-induced radical polymerization of HBPE-MA was performed in the presence of 2-methyl-1-[4-(methylthio) phenyl]-2-morpholinopropan-2-one (Irgacure 907), which acts as a photoinitiator in the solid film state and yields an insoluble cured film upon ultraviolet irradiation. Polymer Journal (2010) 42, 790-794; doi:10.1038/pj.2010.74
引用
收藏
页码：790 / 794
页数：5
相关论文
共 50 条
  • [1] Synthesis of a photocrosslinkable hyperbranched polyester containing methacryloyl groups by the reaction of 1,4-bis(chloromethyl)benzene with 1,3,5-benzenetricarboxylic acid followed by reaction with methacrylic acid
    Ken Maruyama
    Toshiaki Hirabayashi
    Hiroto Kudo
    Tadatomi Nishikubo
    Polymer Journal, 2010, 42 : 790 - 794
  • [2] Synthesis of photocrosslinkable hyperbranched polyesters with terminal methacryloyl groups by the one-pot polyaddition of bis(oxetane)s with 1,3,5-benzenetricarboxylic acid and methacrylic acid
    Nishikubo, T
    Kudo, H
    Maruyama, K
    Nakagami, T
    Miyabe, H
    POLYMER JOURNAL, 2006, 38 (05) : 447 - 456
  • [3] Synthesis of Photocrosslinkable Hyperbranched Polyesters with Terminal Methacryloyl Groups by the One-pot Polyaddition of Bis(oxetane)s with 1,3,5-Benzenetricarboxylic Acid and Methacrylic Acid
    Tadatomi Nishikubo
    Hiroto Kudo
    Ken Maruyama
    Takehiko Nakagami
    Hidekazu Miyabe
    Polymer Journal, 2006, 38 : 447 - 456
  • [4] Synthesis of Photocrosslinkable Hyperbranched Polysulfide Containing Methacryloyl Groups by the Reaction of Bis(oxetane) with Thiocyanuric Acid Followed by the Reaction with Methacrylic Anhydride
    Maruyama, Ken
    Koike, Naoyuki
    Sugimoto, Hiroki
    Kudo, Hiroto
    Nishikubo, Tadatomi
    POLYMER JOURNAL, 2009, 41 (10) : 855 - 859
  • [5] Synthesis of Photocrosslinkable Hyperbranched Polysulfide Containing Methacryloyl Groups by the Reaction of Bis(oxetane) with Thiocyanuric Acid Followed by the Reaction with Methacrylic AnhydrideHyperbranched Polysulfide Containing Methacryloyl Groups
    Ken Maruyama
    Naoyuki Koike
    Hiroki Sugimoto
    Hiroto Kudo
    Tadatomi Nishikubo
    Polymer Journal, 2009, 41 : 855 - 859
  • [6] Synthesis of Hyperbranched Poly(ester)s with Pendant Hydroxy Groups by the Polyaddition of Bis(oxetane)s with 1,3,5-Benzenetricarboxylic Acid
    Tadatomi Nishikubo
    Hiroto Kudo
    Takehiko Nakagami
    Polymer Journal, 2006, 38 : 145 - 152
  • [7] Synthesis of hyperbranched poly(ester)s with pendant hydroxy groups by the polyaddition of bis(oxetane)s with 1,3,5-benzenetricarboxylic acid
    Nishikubo, T
    Kudo, H
    Nakagami, T
    POLYMER JOURNAL, 2006, 38 (02) : 145 - 152
  • [8] REACTION OF 1,4-BIS(DIMETHYLSILYL)BENZENE WITH ACRYLIC AND METHACRYLIC ACIDS AND THEIR DERIVATIVES
    GVERDTSITELI, IM
    DOKSOPULO, TP
    CHIKOVANI, EI
    ZHURNAL OBSHCHEI KHIMII, 1977, 47 (02): : 352 - 355
  • [9] SYNTHESIS AND CRTYSTAL STRUCTURE OF LUTETIUM (Ⅲ) COMPLEX WITH 1,3,5-BENZENETRICARBOXYLIC ACID
    Duan Zhi-Bang Wei Ge-Cheng Jin Zhong-Sheng Ni Jia-ZanChangchun Institute of Applied Chemistry
    结构化学, 1992, (05) : 347 - 350
  • [10] Synthesis and crystal structure of cadmium coordination polymer with 1,3,5-benzenetricarboxylic acid
    Guo, X. -H.
    Zhang, X.
    Zhao, L. -Y.
    Zhang, N. -X.
    Yi, Z. -H.
    CRYSTALLOGRAPHY REPORTS, 2015, 60 (06) : 860 - 864
12345