Resonant Band-Edge Emissive States in Strongly Confined CsPbBr3 Perovskite Nanoplatelets

被引：10

作者：

Socie, Etienne ^{[1
]}

Vale, Brener R. C. ^{[1
,2
]}

Terpstra, Aaron T. ^{[1
]}

Schiavon, Marco A. ^{[2
]}

Moser, Jacques-E ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Photochem Dynam Grp, Inst Chem Sci & Engn, CH-1015 Lausanne, Switzerland

[2] Univ Fed Sao Joao del Rei, Dept Ciencias Nat, Grp Pesquisa Quim Mat, BR-36301160 Sao Joao Del Rei, MG, Brazil

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2021年 / 125卷 / 26期

基金：

瑞士国家科学基金会;

关键词：

LIGHT-EMITTING-DIODES; EXCITON LOCALIZATION; CUINS2; NANOCRYSTALS; COLLOIDAL SYNTHESIS; ENERGY-TRANSFER; DYNAMICS; RECOMBINATION; EVOLUTION; CARRIERS; ORIGIN;

D O I：

10.1021/acs.jpcc.1c01353

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Strongly confined, fully inorganic cesium lead halide perovskite nanocrystals are of great promise for light-emitting devices in the blue spectral range owing to their high photoluminescence quantum yields. A combination of broadband fluorescence up-conversion and transient absorption spectroscopies was used to study early exciton dynamics in quasi-1D CsPbBr3 nanoplatelets (3 x 4 x 23 nm3, NPls). This allowed to reveal emitting band-edge states in the NPls that form instantaneously upon photoexcitation and then relax within the first picosecond to lower energy confined hole states (CHSs). The influence of the pump excitation intensity on the latter process was further scrutinized. The band-edge population lifetime was found to increase with the rise of the photon fluence due to CHS filling. When the concentration of NPls in solution becomes very high, nanoparticles overlap, resulting in a decrease in their external absorption cross-section and an increase in the emission Stokes shift due to photon reabsorption.

引用

页码：14317 / 14325

页数：9

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