3-{2-[2-(Diphenylmethylene)hydrazinyl]thiazol-4-yl}-2H-chromen-2-one

被引:4
作者
Arshad, Afsheen [2 ]
Osman, Hasnah [2 ]
Chan, Kit Lam [3 ]
Yeap, Chin Sing [1 ]
Fun, Hoong-Kun [1 ]
机构
[1] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia
[2] Univ Sains Malaysia, Sch Chem Sci, George Town 11800, Malaysia
[3] Univ Sains Malaysia, Sch Pharmaceut Sci, George Town 11800, Malaysia
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词
COUMARIN;
D O I
10.1107/S1600536810023627
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C25H17N3O2S, the coumarin ring system is essentially planar with a maximum deviation of 0.019 (2) angstrom. A weak intramolecular C-H center dot center dot center dot O hydrogen bond stabilizes the molecular structure, so that the coumarin plane is approximately coplanar with the thiazole ring, making a dihedral angle of 2.5 (10)degrees. The two phenyl rings are nearly perpendicular to each other, with a dihedral angle of 81.44 (12)degrees. In the crystal structure, the molecules are linked into an infinite chain along the b axis by intermolecular C-H center dot center dot center dot O hydrogen bonds. Weak C-H center dot center dot center dot pi interactions are observed between the chains.
引用
收藏
页码:O1788 / U448
页数:12
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