A New 3D Supramolecular Manganese(II) Complex Constructed from Benzimidazole-5,6-dicarboxylate and Oxalate: Synthesis, Structural, and Magnetic Properties

被引：7
|
作者：
Geng, Jin-Peng [1 ]
Wang, Zhao-Xi [1 ]
Wu, Qiong-Fang [1 ]
Li, Ming-Xing [1 ,3 ]
Xiao, Hong-Ping [2 ]
机构：
[1] Shanghai Univ, Dept Chem, Coll Sci, Shanghai 200444, Peoples R China
[2] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Peoples R China
[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2011年 / 637卷 / 02期
基金：
中国国家自然科学基金;
关键词：
Manganese; Benzimidazole-5,6-dicarboxylate acid; X-ray diffraction; IR spectroscopy; Magnetic properties; COORDINATION POLYMERS; ACID; PENTAHYDRATE; LUMINESCENCE; TOPOLOGY; LIGANDS; SERIES; MN(II); 2D;
D O I：
10.1002/zaac.201000295
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new manganese(II) complex [Mn-3(bidc)(2)(C2O4)(H2O)(10)](n) (1) (bidc = benzimidazole-5,6-dicarboxylate) was synthesized and characterized by X-ray crystallography. X-ray diffraction shows that complex 1 has a neutral, one-dimensional (ID) brick wall chain structure. With the intramolecular and intermolecular hydrogen bonding interactions, the adjacent chains are joined into a 3D suparmolecular architecture. IR spectroscopy and variable temperature magnetic susceptibility measurements were made, which indicated weak antiferromagnetic coupling between the Mn-II ions in complex 1.
引用
收藏
页码：301 / 305
页数：5
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