A New 3D Supramolecular Manganese(II) Complex Constructed from Benzimidazole-5,6-dicarboxylate and Oxalate: Synthesis, Structural, and Magnetic Properties

被引：7
|
作者：
Geng, Jin-Peng [1 ]
Wang, Zhao-Xi [1 ]
Wu, Qiong-Fang [1 ]
Li, Ming-Xing [1 ,3 ]
Xiao, Hong-Ping [2 ]
机构：
[1] Shanghai Univ, Dept Chem, Coll Sci, Shanghai 200444, Peoples R China
[2] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Peoples R China
[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2011年 / 637卷 / 02期
基金：
中国国家自然科学基金;
关键词：
Manganese; Benzimidazole-5,6-dicarboxylate acid; X-ray diffraction; IR spectroscopy; Magnetic properties; COORDINATION POLYMERS; ACID; PENTAHYDRATE; LUMINESCENCE; TOPOLOGY; LIGANDS; SERIES; MN(II); 2D;
D O I：
10.1002/zaac.201000295
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new manganese(II) complex [Mn-3(bidc)(2)(C2O4)(H2O)(10)](n) (1) (bidc = benzimidazole-5,6-dicarboxylate) was synthesized and characterized by X-ray crystallography. X-ray diffraction shows that complex 1 has a neutral, one-dimensional (ID) brick wall chain structure. With the intramolecular and intermolecular hydrogen bonding interactions, the adjacent chains are joined into a 3D suparmolecular architecture. IR spectroscopy and variable temperature magnetic susceptibility measurements were made, which indicated weak antiferromagnetic coupling between the Mn-II ions in complex 1.
引用
收藏
页码：301 / 305
页数：5
相关论文
共 44 条
  • [1] Synthesis, structures, and luminescence of lanthanide coordination polymers constructed from benzimidazole-5,6-dicarboxylate and oxalate ligands
    Sun, Ya-Guang
    Yu, Wan
    Wang, Lei
    Rong, Shu-Ting
    Wu, Yong-Li
    Ding, Fu
    Zhang, Wan-Zhong
    Gao, En-Jun
    INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (04) : 479 - 483
  • [2] Synthesis, Crystal Structure and Magnetic Properties of Mn(II) Benzimidazole-5,6-dicarboxylate Complex
    Lin Pei-Xi
    Kang Xin-Ping
    An Zhe
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2011, 27 (07) : 1446 - 1450
  • [3] Synthesis, structure, photoluminescence and magnetism of 3d-4f heterometallic coordination polymers bearing benzimidazole-5,6-dicarboxylate
    Sun, Ya-Guang
    Zong, Wen-Hui
    Xiong, Gang
    Guo, Mei-Yan
    Ding, Fu
    Wang, Shu-Ju
    You, Li-Xin
    Ren, Bao-Yi
    Xu, Zhen-He
    Gao, En-Jun
    POLYHEDRON, 2014, 83 : 68 - 76
  • [4] Synthesis, Crystal Structures, and Thermal Analyses of Copper(II) and Manganese(II) Mixed-Ligand Coordination Polymers Constructed from Benzimidazole-5,6-dicarboxylic Acid and N-Donor Ligands
    Wang, Yongli
    Wei, Zhen
    Geng, Lili
    Yang, Xiaoqian
    An, Xiaoying
    Liang, Siyu
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2015, 641 (11): : 1964 - 1968
  • [5] 2D and 3D lanthanide coordination polymers constructed from benzimidazole-5,6-dicarboxylic acid and sulfate bridged secondary building units
    Wang, Zhao-Xi
    Wu, Qiong-Fang
    Liu, Hong-Jiang
    Shao, Min
    Xiao, Hong-Ping
    Li, Ming-Xing
    CRYSTENGCOMM, 2010, 12 (04): : 1139 - 1146
  • [6] Syntheses, structures and luminescence properties of two series of 3D lanthanide coordination polymers based on benzimidazole-5,6-dicarboxylic acid and oxalate
    Chen, Tian-Li
    Yu, Xiao-Yang
    Zhao, Xiang
    Luo, Yu-Hui
    Yang, Jia-Jun
    Zhang, Hong
    Chen, Xin
    INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 23 : 74 - 77
  • [7] Synthesis, Structure and Magnetic Properties of a 3D Manganese(II) Framework Featuring a Heptanodal Topology and Tube-in-Tube Dihelical Chains
    Chen, Zilu
    Quan, Lixia
    Liu, Long
    Wang, Yifei
    Zou, Huahong
    Liang, Fupei
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2015, (08) : 1463 - 1468
  • [8] Hydrothermal Synthesis, Crystal Structure, and Properties of A 3D Holmium(III) Coordination Framework Based on the Pyridine 2,6-dicarboxylate and Oxalate Ligands
    Feng, Xun
    Shi, Xin-Ge
    Sun, Qian
    Wang, Li-Ya
    Zhao, Jian-She
    Liu, Yong-Yong
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2010, 40 (07) : 479 - 484
  • [9] A New 3D Manganese(II) Coordination Polymer with 4,4-Dicarboxy-2,2′-bipyridine and 1,10-Phenanthroline: Synthesis, Structural, and Magnetic Properties
    Cao, Ting-Ting
    Ma, Yue
    Yang, Chun
    Liao, Dai-Zheng
    Yan, Shi-Ping
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2010, 636 (15): : 2704 - 2708
  • [10] Novel metal-organic and supramolecular 3D frameworks constructed from flexible biphenyl-2,5,3′-tricarboxylate blocks: Synthesis, structural features and properties
    You, Ao
    Li, Yu
    Zhang, Ze-Min
    Zou, Xun-Zhong
    Gu, Jin-Zhong
    Kirillov, Alexander M.
    Chen, Jin-Wei
    Chen, Yun-Bo
    JOURNAL OF MOLECULAR STRUCTURE, 2017, 1145 : 339 - 346
12345