Structure analysis of photo-induced triplet phenylnitrene using synchrotron radiation

被引：19
|
作者：
Kawano, M [1 ]
Takayama, T
Uekusa, H
Ohashi, Y
Ozawa, Y
Matsubara, K
Imabayashi, H
Mitsumi, M
Toriumi, K
机构：
[1] Tokyo Inst Technol, Dept Chem & Mat Sci, Meguro Ku, Tokyo 1528551, Japan
[2] Japan Sci & Technol Corp, CREST, Kawaguchi 3320012, Japan
[3] Himeji Inst Technol, Dept Mat Sci, Himeji, Hyogo 6781297, Japan
来源：
CHEMISTRY LETTERS | 2003年 / 32卷 / 10期
关键词：
D O I：
10.1246/cl.2003.922
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystal structures of [(PhCH2)(2)NH2](+)[m-C6H4(N-3)-(COO)](-) before and after UV-irradiation were analyzed at 25 K by using an X-ray vacuum camera set up at the synchrotron laboratory (SPring-8). The C-N (nitrene) bond distance in the triplet state of the photo-induced m-carboxyphenylnitrene is determined to be 1.34(4) Angstrom.
引用
收藏
页码：922 / 923
页数：2
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