A Novel Polycatechol/Ordered Mesoporous Carbon Composite Film Modified Electrode and Its Electrocatalytic Application

被引：21
作者：
Bai, Jing [1 ]
Bo, Xiangjie [1 ]
Qi, Bin [1 ]
Guo, Liping [1 ]
机构：
[1] NE Normal Univ, Fac Chem, Changchun 130024, Peoples R China
来源：
ELECTROANALYSIS | 2010年 / 22卷 / 15期
基金：
中国国家自然科学基金;
关键词：
Ordered mesoporous carbon; Polycatechol; Electropolymerization; Electroeatalysis; NADH; LOW POTENTIAL DETECTION; FERROCENECARBOXYLIC ACID; ELECTROPOLYMERIZED FILMS; ADENINE-DINUCLEOTIDE; NADH; OXIDATION; ELECTROCHEMISTRY; PERMSELECTIVITY; POLYMERIZATION; NANOTUBES;
D O I：
10.1002/elan.200900538
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Polycatechol (PCC) was prepared by electropolymerizing catechol (CC) on the surface of an ordered mesoporous carbon (OMC) modified electrode for the first time Scanning electron microscopy (SEM) and cyclic x,voltammetry (CV) were used to characterize the structure and electrochemical behaviors of PCC/OMC nanocomposite film Compared with the bare GC and OMC/GC electrodes. the PCC/OMC/GC electrode exhibits a good electrocatalysis toward the oxidation of NADH at (U) V with a high sensitivity (8 7 mA/mM) These make PCC/OMC/GC electrode a promising candidate for stable and efficient electrochemical sensors for the detection of NADH
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页码：1750 / 1756
页数：7
相关论文
共 43 条
  • [1] Bard A.J, 2002, Student Solutions Manual to accompany Electrochemical Methods: Fundamentals and Applicaitons, V2e
  • [2] PALLADIUM CATALYZED ALLYLATION OF REFORMATSKY REAGENTS - SYNTHESIS OF GAMMA,DELTA-UNSATURATED ESTERS
    BOLDRINI, GP
    MENGOLI, M
    TAGLIAVINI, E
    TROMBINI, C
    UMANIRONCHI, A
    [J]. TETRAHEDRON LETTERS, 1986, 27 (35) : 4223 - 4226
  • [3] MODIFICATION OF ELECTRODE SURFACES WITH OXIDIZED PHENOLS TO CONFER SELECTIVITY TO AMPEROMETRIC BIOSENSORS FOR GLUCOSE DETERMINATION
    CHRISTIE, IM
    VADGAMA, P
    LLOYD, S
    [J]. ANALYTICA CHIMICA ACTA, 1993, 274 (02) : 191 - 199
  • [4] Low potential detection of NADH at titanium-containing MCM-41 modified glassy carbon electrode
    Dai, Zhihui
    Lu, Guofei
    Bao, Jianchun
    Huang, Xiaohua
    Ju, Huangxian
    [J]. ELECTROANALYSIS, 2007, 19 (05) : 604 - 607
  • [5] Modification of catechol polymer redox properties during electropolymerization in the presence of aliphatic amines
    Davis, J
    Vaughan, DH
    Cardosi, MF
    [J]. ELECTROCHIMICA ACTA, 1998, 43 (3-4) : 291 - 300
  • [6] Ordered porous materials for emerging applications
    Davis, ME
    [J]. NATURE, 2002, 417 (6891) : 813 - 821
  • [7] Boron-doped carbon nanotubes modified electrode for electroanalysis of NADH
    Deng, Chunyan
    Chen, Jinhua
    Chen, XiaoLi
    Mao, Chunhui
    Nie, Zhou
    Yao, Shouzhuo
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2008, 10 (06) : 907 - 909
  • [8] Direct electron transfer and electrocatalysis of hemoglobin adsorbed on mesoporous carbon through layer-by-layer assembly
    Feng, Jiu-Ju
    Xu, Jing-Juan
    Chen, Hong-Yuan
    [J]. BIOSENSORS & BIOELECTRONICS, 2007, 22 (08) : 1618 - 1624
  • [9] Electrooxidative polymerization of phenothiazine derivatives on screen-printed carbon electrode and its application to determine NADH in flow injection analysis system
    Gao, Q
    Wang, WD
    Ma, Y
    Yang, XR
    [J]. TALANTA, 2004, 62 (03) : 477 - 482
  • [10] ELECTROPOLYMERIZED FILMS TO PREVENT INTERFERENCES AND ELECTRODE FOULING IN BIOSENSORS
    GEISE, RJ
    ADAMS, JM
    BARONE, NJ
    YACYNYCH, AM
    [J]. BIOSENSORS & BIOELECTRONICS, 1991, 6 (02) : 151 - 160
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