Ionic liquids enhance the electrochemical CO2 reduction catalyzed by MoO2

被引：79

作者：

Oh, Yeonji ^{[1
]}

Hu, Xile ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, EPFL ISIC LSCI, Inst Chem Sci & Engn, Lab Inorgan Synth & Catalysis, CH-1015 Lausanne, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 71期

基金：

欧洲研究理事会;

关键词：

SELECTIVE CONVERSION; CARBON-DIOXIDE; ELECTRODES; ELECTROREDUCTION; DEPENDENCE; EFFICIENCY; MECHANISM; MEDIA;

D O I：

10.1039/c5cc05263g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Several imidazolium-based ionic liquids significantly enhance the activity of MoO2 for electrochemical reduction of CO2. The over-potential of CO2 reduction is as low as 40 mV. The ionic liquids act as both electrolytes and co-catalysts, which not only leads to lower overpotentials, but also alters the product selectivity.

引用

收藏

页码：13698 / 13701

页数：4

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