A structure-directing method to prepare semiconductive zeolitic cluster-organic frameworks with Cu3I4 building units

被引:46
作者
Kang, Yao [1 ]
Fang, Wei-Hui [1 ]
Zhang, Lei [1 ]
Zhang, Jian [1 ]
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
关键词
BORON IMIDAZOLATE FRAMEWORKS; CATALYSTS; TOPOLOGY; POLYMER; IODIDE;
D O I
10.1039/c5cc02598b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two semiconductive cluster-organic frameworks based on Cu4I4 and Cu3I4 building units were obtained by the use of different organic structure-directing agents; the latter Cu3I4 nodes are tetra-hedrally connected through 1,4-diazabicyclo[2.2.2] octane (DABCO) linkers and Cu-I bridges, giving rise to a zeolitic framework with SOD topology.
引用
收藏
页码:8994 / 8997
页数:4
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