Multiple Catalysis with Two Chiral Units: An Additional Dimension for Asymmetric Synthesis

被引：132

作者：

Piovesana, Susy ^{[1
]}

Schietroma, Daniele M. Scarpino ^{[1
]}

Bella, Marco ^{[1
]}

机构：

[1] Univ Roma La Sapienza, Dipartimento Chim, I-00185 Rome, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 28期

关键词：

asymmetric catalysis; multifunctional catalysis; multiple catalysis; organocatalysis; transition metals; DIELS-ALDER REACTION; TRANSITION-METAL CATALYSIS; ORGANOCATALYTIC CONJUGATE ADDITION; COMBINATORIAL HOMOGENEOUS CATALYSIS; AZA-HENRY REACTION; MICHAEL ADDITION; ALPHA; BETA-UNSATURATED KETONES; TRANSFER HYDROGENATION; BIDENTATE LIGANDS; ENANTIOSELECTIVE CATALYSIS;

D O I：

10.1002/anie.201005955

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This Minireview focuses on asymmetric reactions mediated by two distinct chiral catalysts (chiral multiple catalysis). Initially, this approach appears unconventional, but indeed it allows a fast multidimensional optimization and fine-tuning of the catalytic system required to perform a given transformation. Herein, this emerging concept is presented and its potential applications are highlighted. Divide et Impera: A newly emerging aspect of catalysis that involves the use of two chiral catalysts simultaneously is described (see picture). This Minireview highlights the features of the two-catalyst reactions and the synthetic applications of the methods. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6216 / 6232

页数：17

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