Influence of thermal treatment on the properties and intermolecular interactions of epoxidized natural rubber-salt systems

被引：3
|
作者：
Zainal, Nurul Fatahah Asyqin [2 ]
Ramli, Hairunnisa [2 ]
Fritz, Margarethe [3 ]
Abetz, Volker [3 ,4 ]
Chan, Chin Han [1 ]
机构：
[1] Univ Teknol MARA, Fac Sci Appl, Shah Alam 40450, Selangor, Malaysia
[2] Univ Teknol MARA, Ctr Fdn Studies, Kampus Dengkil, Dengkil 43800, Selangor, Malaysia
[3] Univ Hamburg, Inst Phys Chem, Martin Luther King Pl 6, D-20146 Hamburg, Germany
[4] Helmholtz Zentrum Hereon, Inst Membrane Res, Max Planck Str 1, D-21502 Geesthacht, Germany
来源：
PURE AND APPLIED CHEMISTRY | 2021年 / 93卷 / 10期
关键词：
Centenary of macromolecules; dielectric properties; epoxidized natural rubber; glass transition temperature; intermolecular interaction; IUPAC Polymer Division; macrogel; microgel; thermal treatment; POLY(ETHYLENE OXIDE); IONIC-CONDUCTIVITY; STRUCTURAL-CHARACTERIZATION; POLYMER ELECTROLYTES; LATEX; EPOXIDATION; TEMPERATURE; BEHAVIOR; GLASS; GEL;
D O I：
10.1515/pac-2020-0904
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The influence of thermal treatment on the thermal stability, thermal properties, dielectric properties and intermolecular interaction of binary epoxidized natural rubber (ENR)-salt systems, which may be a candidate for solid polymer electrolytes (SPEs) was investigated. Solubility of salt in ENR enhances, which may be due to the disruption of the lightly-crosslinked microgel under heat treatment. The increase in the ionic conductivities of the thermally treated ENR SPEs at constant salt content is correlated to the higher glass transition temperatures, development of percolation network and higher extent of intermolecular interactions between ENR and charged entities in this study.
引用
收藏
页码：1119 / 1139
页数：21
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