The relevance of laboratory studies on delayed ettringite formation to DEF in field concretes

Many laboratory studies of delayed ettringite formation (DEF) have been conducted on thin mortar bar specimens, heat treated, and then immersed in water. Under these conditions, rapid diffusion of alkali hydroxide into the surrounding water occurs and necessarily reduces the alkali hydroxide concentration of the mortar pore solution. Results reported recently by Famy indicate that the DEF process is triggered as a consequence of such leaching. When it is prevented by immersion into alkali hydroxide solution instead of water DEF expansion is delayed or prevented entirely. Results reported by Zhang indicate that 51-mm mortar cubes behave differently than more leaching-susceptible mortar bars when exposed to the same wet environment. Mortars that show severe DEF as mortar bars remain almost free of DEF symptoms if they are stored as cubes, even after 900 days. Attention is called to the fact that DEF in concrete is found commonly in thick concrete members where the possibility of leaching is remote. For such concrete, the reduction in internal alkali hydroxide concentration that occurs with ASR can substitute for the effect of leaching. It is postulated that without effective reduction of alkali hydroxide concentration by one or the other process, DEF remains latent. (C) 2001 Elsevier Science Ltd. All rights reserved.