Modern Methods for Producing Acetic Acid from Methane: New Trends (A Review)

被引:12
作者
Ezhova, N. N. [1 ]
Kolesnichenko, N., V [1 ]
Maximov, A. L. [1 ]
机构
[1] Russian Acad Sci, Topchiev Inst Petrochem Synth, Moscow 119991, Russia
基金
俄罗斯科学基金会;
关键词
synthesis of acetic acid from methane over heterogeneous catalysts; synthesis of acetic acid via syngas; low-temperature" oxidative methane conversion; one- and two-step procedures for methane conversion to acetic acid; direct synthesis of acetic acid from methane and carbon dioxide; DIMETHYL ETHER CARBONYLATION; FISCHER-TROPSCH SYNTHESIS; CARBON-DIOXIDE; DIRECT CONVERSION; ZEOLITE CATALYST; METHYL ACETATE; AROMATIC-HYDROCARBONS; EFFICIENT CATALYSTS; COMPOSITE ZEOLITE; DIRECT OXIDATION;
D O I
10.1134/S0965544122010078
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Recent achievements in the development of new methods for producing acetic acid (AA) from methane using heterogeneous catalysts are summarized and systematized Modern heterogeneous-catalytic processes of methane conversion to AA via syngas and alternative one- and two-step AA production procedures via "low-temperature" oxidative methane conversion (via oxidative coupling, oxyhalogenation, oxidation into methanol, or oxidative transformations of CH4 in the presence of carbon oxides) are considered. The major attention is paid to the one-step AA synthesis by methane oxydation with carbon dioxide (by carboxylation reaction). Specific features of heterogeneous catalysts recently developed for this reaction are discussed.
引用
收藏
页码:40 / 61
页数:22
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