CuO modified KIT-6 as a high-efficiency catalyst for energy-efficient amine solvent regeneration

被引：53

作者：

Zhang, Rui ^{[1
,2
,4
]}

Li, Ting ^{[1
]}

Zhang, Yiming ^{[1
]}

Ha, Junyu ^{[1
]}

Xiao, Yuting ^{[1
]}

Li, Chao'en ^{[3
]}

Zhang, Xiaowen ^{[1
,2
,4
]}

Luo, He'an ^{[1
]}

机构：

[1] Xiangtan Univ, Coll Chem Engn, Xiangtan 411105, Hunan, Peoples R China

[2] Xiangtan Univ, Foshan Green Intelligent Mfg Res Inst, Foshan 528300, Guangdong, Peoples R China

[3] CSIRO Energy, 71 Normanby Rd, Clayton North, Vic 3169, Australia

[4] Engn Res Ctr Low Carbon Chem Proc & Resource Util, Xiangtan 411105, Hunan, Peoples R China

来源：

SEPARATION AND PURIFICATION TECHNOLOGY | 2022年 / 300卷

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

Energy reduction; Catalytic CO 2 desorption; Amine solution; CARBON-DIOXIDE CAPTURE; CO2-LOADED MEA SOLUTION; CO2; CAPTURE; MESOPOROUS SILICA; DESORPTION; PERFORMANCE; ABSORPTION; OXIDE; CONSUMPTION; TECHNOLOGY;

D O I：

10.1016/j.seppur.2022.121702

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Chemical absorption using an amine solution is currently the most common and effective CO2 capture technology. However, this method suffers from the high energy consumption for solvent regeneration, which hinders its industrial application. It has been proven that catalytic CO2 desorption technology using solid acid catalysts is a promising way to lower regeneration energy consumption. In this study, three transition metal oxides (CuO, NiO and Fe2O3) modified mesoporous molecular sieve (KIT-6) catalysts were prepared and then utilized to catalyze the regeneration process of a rich CO2 monoethanolamine solution. The findings demonstrated that the four catalysts enhanced the CO2 desorption rate and reduced the relative energy consumption. The relative energy consumptions (%) for the amine solvent regeneration using the prepared catalysts follows the order of: blank test (100) > KIT-6 (79.8) > Fe2O3-KIT-6 (76.5) > NiO-KIT-6 (75.4) > CuO-KIT-6 (66.6). The superior catalytic activity of the CuO-KIT-6 catalyst is attributed to its high Bronsted acid sites and large mesoporous surface area. The cyclic test results revealed that after five cycles of absorption-desorption, the catalytic activity of CuO-KIT-6 was still kept at 93.4%. In addition, a potential CuO-KIT-6 catalyst-based catalytic CO2 desorption mechanism was suggested. This study provides a new idea to design and prepare a high-efficiency catalyst to promote regeneration of the CO2-loaded amine solution, lower the regeneration energy consumption, and ultimately increase the economic viability of the catalytic regeneration method.

引用

页数：11

共 58 条

[41]

Gao H., Liu S., Gao G., Luo X., Liang Z., Hybrid behavior and mass transfer performance for absorption of CO2 into aqueous DEEA/PZ solutions in a hollow fiber membrane contactor, Sep. Purif. Technol., 201, pp. 291-300, (2018)

[42]

Nwaoha C., Saiwan C., Tontiwachwuthikul P., Supap T., Rongwong W., Idem R., Al-Marri M.J., Benamor A., Carbon dioxide (CO2) capture: Absorption-desorption capabilities of 2-amino-2-methyl-1-propanol (AMP), piperazine (PZ) and monoethanolamine (MEA) tri-solvent blends, J. Nat. Gas Sci. Eng., 33, pp. 742-750, (2016)

[43]

Zhang X., Zhang R., Liu H., Gao H., Liang Z., Evaluating CO2 desorption performance in CO2-loaded aqueous tri-solvent blend amines with and without solid acid catalysts, Appl. Energy, 218, pp. 417-429, (2018)

[44]

Narku-Tetteh J., Muchan P., Saiwan C., Supap T., Idem R., Selection of components for formulation of amine blends for post combustion CO2 capture based on the side chain structure of primary, secondary and tertiary amines, Chem. Eng. Sci., 170, pp. 542-560, (2017)

[45]

Xing L., Wei K., Li Q., Wang R., Zhang S., Wang L., One-Step Synthesized SO42–/ZrO2-HZSM-5 Solid Acid Catalyst for Carbamate Decomposition in CO2 Capture, Environm. Sci. Technol., 54, pp. 13944-13952, (2020)

[46]

Xing L., Wei K., Li Y., Fang Z., Li Q., Qi T., An S., Zhang S., Wang L., TiO2 Coating Strategy for Robust Catalysis of the Metal-Organic Framework toward Energy-Efficient CO2 Capture, Environm. Sci. Technol., 55, pp. 11216-11224, (2021)

[47]

Sun Q., Li T., Mao Y., Gao H., Sema T., Wang S., Liu L., Liang Z., Reducing Heat Duty of MEA Regeneration Using a Sulfonic Acid-Functionalized Mesoporous MCM-41 Catalyst, Ind. Eng. Chem. Res., 60, pp. 18304-18315, (2021)

[48]

Zhang X., Hong J., Liu H., Luo X., Olson W., Tontiwachwuthikul P., Liang Z., SO42−/ZrO2 supported on γ-Al2O3 as a catalyst for CO2 desorption from CO2-loaded monoethanolamine solutions, AIChE J., 64, pp. 3988-4001, (2018)

[49]

Lai Q., Toan S., Assiri M.A., Cheng H., Russell A.G., Adidharma H., Radosz M., Fan M., Catalyst-TiO(OH)2 could drastically reduce the energy consumption of CO2 capture, Nat. Commun., 9, pp. 1-7, (2018)

[50]

Xia Y., Dai H., Jiang H., Zhang L., Deng J., Liu Y., Three-dimensionally ordered and wormhole-like mesoporous iron oxide catalysts highly active for the oxidation of acetone and methanol, J. Hazard. Mater., 186, pp. 84-91, (2011)

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