Simultaneous production of glucose, furfural, and ethanol organosolv lignin for total utilization of high recalcitrant biomass by organosolv pretreatment

被引：107

作者：

Choi, June-Ho ^{[1
]}

Jang, Soo-Kyeong ^{[1
]}

Kim, Jong-Hwa ^{[1
]}

Park, Se-Yeong ^{[1
]}

Kim, Jong-Chan ^{[1
]}

Jeong, Hanseob ^{[2
]}

Kim, Ho-Yong ^{[3
]}

Choi, In-Gyu ^{[1
,4
,5
]}

机构：

[1] Seoul Natl Univ, Dept Forest Sci, Seoul 08826, South Korea

[2] Natl Inst Forest Sci, Dept Forest Prod, Div Wood Chem & Microbiol, Seoul 02455, South Korea

[3] Korea Res Inst Chem Technol, Ctr Biobased Chem, Daejeon 34114, South Korea

[4] Seoul Natl Univ, Res Inst Agr & Life Sci, Seoul 08826, South Korea

[5] Seoul Natl Univ, Inst Green Bio Sci & Technol, Pyeongchang 25354, South Korea

来源：

RENEWABLE ENERGY | 2019年 / 130卷

关键词：

Ethanol organosolv pretreatment; Glucose; Ethanol organosolv lignin; Furfural; Separation; Total utilization; COMBINED SEVERITY FACTORS; FUEL RANGE ALKANES; ENZYMATIC-HYDROLYSIS; LIGNOCELLULOSIC BIOMASS; RICE STRAW; PHYSICOCHEMICAL CHARACTERIZATION; LIRIODENDRON-TULIPIFERA; ACID PRETREATMENT; BIOGAS PRODUCTION; CHALLENGES;

D O I：

10.1016/j.renene.2018.05.052

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The main purpose of this study was simultaneous production of glucose, ethanol organosolv lignin (EOL), and furfural for total utilization of lignocellulosic biomass to improve economics of biorefinery. The glucose production (37.1 g, under conditions of 160 degrees C with 1% sulfuric acid) was significantly increased after organosolv pretreatment, dissolving 11.4 g of the initial hemicellulose-derived sugars and 22.6 g of the initial lignin. Progressively, organosolv lignin precipitation and furfural production processes were conducted using the liquid hydrolysates obtained after organosolv pretreatment. 12 g of EOL (at 160 degrees C, 1% sulfuric acid) was yielded with the remaining residues of soluble lignin-derived compounds in the liquid hydrolysates. Also, 7.9 g of furfural (at 160 degrees C, 1% sulfuric acid) was observed after additional acid-catalyzed treatment from the liquid hydrolysates. Consequently, a high yield of glucose, EOL and furfural can be obtained simultaneously using ethanol organosolv pretreatment. (C) 2018 Elsevier Ltd. All rights reserved.

引用

页码：952 / 960

页数：9

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