Promotion of oxygen atom transfer in Mo and W enzymes by bicyclic forms of the pterin cofactor

被引:27
作者
McNamara, JP
Joule, JA
Hillier, IH [1 ]
Garner, CD
机构
[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England
[2] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
关键词
D O I
10.1039/b415480k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Density functional theory calculations suggest that bicyclic structures of the "molybdopterin'' in DMSO reductases may have an important catalytic role in oxygen atom transfer reactions.
引用
收藏
页码:177 / 179
页数:3
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