An Efficient Procedure for the Synthesis of Benzoxazole and Benzothiazole Derivatives Using a H2O2/SiO2-FeCl3 System

被引:9
|
作者
Mosslemin, Mohammad Hossein [1 ]
Fazlinia, Abbas [1 ]
机构
[1] Islamic Azad Univ, Yazd Branch, Dept Chem, Yazd 8916871967, Iran
关键词
Aldehydes; benzothiazoles; benzoxazoles; SiO2-FeCl3; H2O2; INDUCED RING ENLARGEMENT; FERRIC-CHLORIDE; SILICA-GEL; PHASE SYNTHESIS; DRY MEDIA; BENZIMIDAZOLES; OXIDATION; WATER; IMIDAZOLINES; ALDEHYDES;
D O I
10.1080/10426501003598630
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A series of benzoxazole and benzothiazoles was readily prepared from the reaction of ortho-aminophenol/ortho-aminothiophenol and aldehydes using solid silica supported ferric chloride (SiO2-FeCl3) as catalyst followed by oxidation with H2O2 under ambient conditions. Some of advantages of this method are a simple and convenient procedure, easy purification, and shorter reaction times. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file.
引用
收藏
页码:2165 / 2170
页数:6
相关论文
共 50 条
  • [1] Fe3O4@SiO2/collagen: An efficient magnetic nanocatalyst for the synthesis of benzimidazole and benzothiazole derivatives
    Ghafuri, Hossein
    Esmaili, Elahe
    Talebi, Majid
    COMPTES RENDUS CHIMIE, 2016, 19 (08) : 942 - 950
  • [2] Preparation of 2-Arylbenzimidazole derivatives using CuO nanoparticles /H2O2 system
    Fazlinia, Abbas
    Sheikh, Setareh
    INORGANIC AND NANO-METAL CHEMISTRY, 2018, 48 (02) : 126 - 130
  • [3] H2O2/HCl as a new and efficient system for synthesis of 2-substituted benzimidazoles
    Bahrami, Kiumars
    Khodaei, Mohammad M.
    Kavianinia, Iman
    JOURNAL OF CHEMICAL RESEARCH, 2006, (12) : 783 - 784
  • [4] Silica-ferric chloride (SiO2-FeCl3) catalyzed selective synthesis of 2-substituted benzimidazole through Csp2-Csp3 bond cleavage of β-ketoesteriamide
    Majumdar, Swapan
    Chakraborty, Ankita
    Bhattacharjee, Subrata
    Debnath, Sudipto
    Maiti, Dilip K.
    TETRAHEDRON LETTERS, 2016, 57 (41) : 4595 - 4598
  • [5] Zn(OAc)2•2H2O: An efficient catalyst for the one-pot synthesis of 2- substituted benzothiazoles
    Digambar, Kokane Balaji
    Varala, Ravi
    Patil, Sudhakar G.
    ORGANIC COMMUNICATIONS, 2022, 15 (04) : 378 - 385
  • [6] AlCl3•6H2O as a Catalyst for Simple and Efficient Synthesis of gem-Dihydroperoxides from Ketones and Aldehydes using Aqueous H2O2
    Azarifar, D.
    Khosravi, K.
    JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2011, 8 (04) : 1006 - 1013
  • [7] Efficient Direct H2O2 Synthesis Enabled by PdPb Nanorings via Inhibiting the O-O Bond Cleavage in O2 and H2O2
    Cao, Kailei
    Yang, Hao
    Bai, Shuxing
    Xu, Yong
    Yang, Chengyong
    Wu, Yu
    Xie, Miao
    Cheng, Tao
    Shao, Qi
    Huang, Xiaoqing
    ACS CATALYSIS, 2021, 11 (03): : 1106 - 1118
  • [8] Simple and Efficient One-Pot Synthesis of 2-Substituted Benzoxazole and Benzothiazole
    Patil, Sachin S.
    Bobade, Vivek D.
    SYNTHETIC COMMUNICATIONS, 2010, 40 (02) : 206 - 212
  • [9] AlCl3.6H2O as a catalyst for simple and efficient synthesis of gem-dihydroperoxides from ketones and aldehydes using aqueous H2O2
    D. Azarifar
    K. Khosravi
    Journal of the Iranian Chemical Society, 2011, 8 : 1006 - 1013
  • [10] Conjugated Nickel Phthalocyanine Derivatives for Heterogeneous Electrocatalytic H2O2 Synthesis
    Sun, Libo
    Jin, Xindie
    Su, Tan
    Fisher, Adrian C.
    Wang, Xin
    ADVANCED MATERIALS, 2024, 36 (17)