Morphology control of ultrafine cuprous oxide powder and its growth mechanism

被引：27

作者：

Cao Yan ^{[1
]}

Wang Yue-jun ^{[1
]}

Zhou Kang-gen ^{[1
]}

Bi Zhen ^{[1
]}

机构：

[1] Cent S Univ, Sch Met Sci & Engn, Changsha 410083, Hunan, Peoples R China

来源：

TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA | 2010年 / 20卷

关键词：

cuprous oxide; morphology control; supersaturation; growth mechanism; CU2O; NANOCRYSTALS; CRYSTALS;

D O I：

10.1016/S1003-6326(10)60042-8

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

Four shapes of Cu2O particles as sphere, cube, truncated octahedron and octahedron were prepared via glucose reduction of Cu(II) under alkaline condition. The products were characterized by XRD and SEM. The effects of the precursor (CuO, Cu(OH)(2)), reaction temperature and glucose concentration on morphology of Cu2O particles were investigated, and the mechanism of morphology control was discussed on the basic theory of crystal nucleation and growth. It is found that the Cu+ supersaturation is remarkably influenced by the precursor kind, reaction temperature and glucose concentration, and the morphology of Cu2O particles can be controlled by the Cu+ supersaturation.

引用

页码：S216 / S220

页数：5

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