Fabrication of β-Ni(OH)2 ∥ γ-Fe2O3 nanostructures for high-performance asymmetric supercapacitors

被引:8
作者
Arul, N. Sabari [1 ]
Han, Jeong In [1 ]
Chen, Pao Chi [2 ]
机构
[1] Dongguk Univ Seoul, Dept Chem & Biochem Engn, Seoul 04620, South Korea
[2] Lunghwa Univ Sci & Technol, Dept Chem & Mat Engn, Taoyuan, Taiwan
基金
新加坡国家研究基金会;
关键词
beta-Ni(OH)(2) nanostructures; gamma-Fe2O3; nanohexagons; Asymmetric supercapacitors; Energy storage and devices; NICKEL FOAM; NEGATIVE ELECTRODE; ENERGY-CONVERSION; NANOSHEETS; CARBON; OXIDE; HETEROSTRUCTURES; CAPACITANCE; HYDROXIDE; BATTERIES;
D O I
10.1007/s10008-017-3769-y
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
In this study, we have fabricated a novel beta-Ni(OH)(2) hierarchical nanostructures (HNs) a gamma-Fe2O3 nanohexagons (NHs) and investigated their potential as electrode material for high-performance asymmetric supercapacitor. The X-ray diffraction and transmission electron microscopy analyses confirmed the presence of beta-Ni(OH)(2) and gamma-Fe2O3 in the obtained products. The electrochemical performance of single electrodes containing beta-Ni(OH)(2) HNs and gamma-Fe2O3 NHs supported on the nickel foam exhibited high specific capacitances of 3232.08 and 1800.06 F g(-1) at the current densities of 3 and 13 mA cm(-2), respectively. As a result, we have fabricated an asymmetric supercapacitor device using beta-Ni(OH)(2) HN gamma-Fe2O3 NH electrodes which exhibited high energy density of 99.28 W h kg(-1) at a power density of 1599.85 W kg(-1), with excellent cycling stability of 89.3% after 5000 cycles. Our results demonstrated that the beta-Ni(OH)(2) HN gamma-Fe2O3 NH electrode material could serve as a potential candidate for energy storage applications.
引用
收藏
页码:293 / 302
页数:10
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