Effective synthesis of 1,3-diselenole-2-selone-4,5-diselenolate (dsis) and its utilization for the synthesis of selenocycle-fused tetraselenafulvalene (TSF) derivatives

被引：19

作者：

Kodani, M

Takimiya, K ^{[1
]}

Aso, Y

Otsubo, T

Nakayashiki, T

Misaki, Y

机构：

[1] Hiroshima Univ, Fac Engn, Dept Appl Chem, Higashihiroshima 7398527, Japan

[2] Kyoto Univ, Grad Sch Engn, Dept Mol Engn, Sakyo Ku, Kyoto 6068501, Japan

来源：

SYNTHESIS-STUTTGART | 2001年 / 11期

关键词：

lithiation; diselenolate ligands; protecting groups; ring-closure reaction; selenium-containing heterocycles;

D O I：

10.1055/s-2001-16755

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A facile and effective synthetic procedure for 1,3-diselenole-2-selone-4.5-diselenolate (dsis, 2) has been established. The utilization of 2 for the synthesis of selenocycle-fused tetraselenafulvalene derivatives is also reported.

引用

页码：1614 / 1618

页数：5

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